A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10

被引：99

作者：

Yang, Yun ^{[1
,2
]}

Pan, Shilie ^{[1
]}

Hou, Xueling ^{[1
]}

Wang, Chuanyi ^{[1
]}

Poeppelmeier, Kenneth R. ^{[3
]}

Chen, Zhaohui ^{[1
,2
]}

Wu, Hongping ^{[1
,2
]}

Zhou, Zhongxiang ^{[1
]}

机构：

[1] Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

[3] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 09期

基金：

中国国家自然科学基金; 美国国家科学基金会;

关键词：

FUNDAMENTAL BUILDING-BLOCKS; CRYSTAL-STRUCTURE DATABASE; BOND-VALENCE PARAMETERS; BORATE CRYSTALS; NLO CRYSTALS; GENERATION; GROWTH; LIB3O5; PENTABORATE; RADIATION;

D O I：

10.1039/c0jm03187a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Single crystals of Li3Cs2B5O10 have been synthesized and its structure determined by single-crystal X-ray diffraction. Li3Cs2B5O10 crystallizes in the non-centrosymmetric space group C222(1) ( No. 20). The structure consists of isolated B5O10 groups that are bridged by LiOn (n = 4, 5) and CsOn (n = 8, 10) polyhedra through their vertex oxygen atoms to form an infinite three-dimensional structure. Li3Cs2B5O10 melts congruently and exhibits a short-wavelength absorption onset at 175 nm. As-prepared Li3Cs2B5O10 is both non-centrosymmetric and phase matchable as supported by second harmonic generation measurements.

引用

页码：2890 / 2894

页数：5

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