A DEMS Study of the Reduction of CO2, CO, and HCHO Pre-Adsorbed on Cu Electrodes: Empirical Inferences on the CO2RR Mechanism

被引：33
|
作者：
Javier, Alnald [1 ]
Chmielowiec, Brian [1 ]
Sanabria-Chinchilla, Jean [1 ]
Kim, Youn-Geun [1 ]
Baricuatro, Jack H. [1 ]
Soriaga, Manuel P. [1 ,2 ]
机构：
[1] CALTECH, Joint Ctr Artificial Photosynthesis, Div Chem & Chem Engn, Pasadena, CA 91125 USA
[2] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
来源：
ELECTROCATALYSIS | 2015年 / 6卷 / 02期
关键词：
ELECTROCHEMICAL REDUCTION; CARBON-DIOXIDE; ELECTROCATALYTIC HYDROGENATION; P-DIHYDROXYBENZENE; ADSORPTION; POLYCRYSTALLINE; HYDROCARBONS; SELECTIVITY; OXIDATION; CU(111);
D O I：
10.1007/s12678-015-0246-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
引用
收藏
页码：127 / 131
页数：5
相关论文
共 50 条
  • [1] Electrocatalytic Reduction of CO2 on Cu and Au/W Electrode Surfaces: Empirical (DEMS) Confirmation of Computational (DFT) Predictions
    Javier, A.
    Baricuatro, J. H.
    Kim, Y-G
    Soriaga, M. P.
    PHYSICAL AND ANALYTICAL ELECTROCHEMISTRY, ELECTROCATALYSIS, AND PHOTOELECTROCHEMISTRY GENERAL SESSION, 2017, 75 (48): : 1 - 17
  • [2] The influence of pH on the reduction of CO and CO2 to hydrocarbons on copper electrodes
    Schouten, Klaas Jan P.
    Gallent, Elena Perez
    Koper, Marc T. M.
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2014, 716 : 53 - 57
  • [3] The Role of Undercoordinated Sites on Zinc Electrodes for CO2 Reduction to CO
    Kang, Mavis Pei Lin
    Kolb, Manuel J.
    Calle-Vallejo, Federico
    Yeo, Boon Siang
    ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (23)
  • [4] Facet Dependence of CO2 Reduction Paths on Cu Electrodes
    Luo, Wenjia
    Nie, Xiaowa
    Janik, Michael J.
    Asthagiri, Aravind
    ACS CATALYSIS, 2016, 6 (01): : 219 - 229
  • [5] Elucidating the structure evolution and reaction mechanism of the Cu-In bimetallic catalysts during CO2RR
    Li, Jiayu
    Zhu, Minghui
    Han, Yi-Fan
    JOURNAL OF CATALYSIS, 2022, 415 : 165 - 173
  • [6] Catalytic role of pre-adsorbed CO in platinum-based catalysts: the reduction of SO2 by CO on PtlAum(CO)n
    Gao, Guo-Ping
    Wei, Shi-Hao
    Gu, Xiao
    Duan, Xiang-Mei
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (31) : 12846 - 12851
  • [7] Influence of S Contamination on CO2 Reduction at Ag Electrodes
    Dufek, Eric J.
    Lister, Tedd E.
    McIlwain, Michael E.
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (11) : B1384 - B1390
  • [8] Assessment of the Degradation Mechanisms of Cu Electrodes during the CO2 Reduction Reaction
    Mom, Rik V.
    Sandoval-Diaz, Luis-Ernesto
    Gao, Dunfeng
    Chuang, Cheng-Hao
    Carbonio, Emilia A.
    Jones, Travis E.
    Arrigo, Rosa
    Ivanov, Danail
    Haevecker, Michael
    Roldan Cuenya, Beatriz
    Schloegl, Robert
    Lunkenbein, Thomas
    Knop-Gericke, Axel
    Velasco-Velez, Juan-Jesus
    ACS APPLIED MATERIALS & INTERFACES, 2023, 15 (25) : 30052 - 30059
  • [9] Spectroelectrochemical Study of CO2 Reduction on TiO2 Electrodes in Acetonitrile
    Mendieta-Reyes, Nestor E.
    Cheuquepan, William
    Rodes, Antonio
    Gomez, Roberto
    ACS CATALYSIS, 2020, 10 (01) : 103 - 113
  • [10] Tuning the Selectivity of Liquid Products of CO2RR by Cu-Ag Alloying
    Xu, Yanzhi
    Li, Changli
    Xiao, Yequan
    Wu, Chenghui
    Li, Yanming
    Li, Yanbo
    Han, Juguang
    Liu, Qinghua
    He, Jingfu
    ACS APPLIED MATERIALS & INTERFACES, 2022, 14 (09) : 11567 - 11574
12345