RETRACTED: Self-assembled chalcopyrite ternary semiconductor CuBSe2 nanocrystals: solvothermal synthesis and characterisation (Retracted Article)

被引:9
作者
Chen, Lin-Jer [1 ]
Liao, Jiunn-Der [1 ]
Chuang, Yu-Ju [1 ]
机构
[1] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 701, Taiwan
关键词
SOLAR-CELLS; THIN-FILMS; CUINSE2; GROWTH; NANOPARTICLES; NANORODS;
D O I
10.1039/c0ce00818d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chalcopyrites are important contenders among thin-film solar cells due to their direct band gap and higher absorption coefficient. Copper-boron-selenium (CuBSe2) is a chalcopyrite material with a near-optimum band gap of similar to 3.13 eV. Semiconductor CuBSe2 nanorods were successfully prepared via a relatively simple and convenient solvothermal route. The device parameters for a single junction CuBSe2 solar cell under AM 1.5 G are as follows: open circuit voltage of 310 mV, short-circuit current of 25.5 mA cm(-2), fill factor of 24%, and a power conversion efficiency of 1.89%. Based on a series of comparative experiments under various reaction conditions, the probable formation mechanism of crystals CuBSe2 nanorods is proposed.
引用
收藏
页码:2909 / 2914
页数:6
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