A short synthesis of optically active Corey lactone by means of the dirhodium(II)-catalyzed intramolecular C-H insertion reaction of an α-diazo ketone

被引：0

作者：

Yakura, T ^{[1
]}

Yamada, S ^{[1
]}

Azuma, M ^{[1
]}

Ueki, A ^{[1
]}

Ikeda, M ^{[1
]}

机构：

[1] Kyoto Pharmaceut Univ, Kyoto 607, Japan

来源：

SYNTHESIS-STUTTGART | 1998年 / 07期

关键词：

dirhodium(II)-catalyzed intramolecular C-H insertion; alpha-diazo ketone; 2-oxocyclopentanecarboxylate; Corey lactone; dirhodium(II) tetraacetate;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active Corey lactone 8 has been synthesized using a dirhodium(II)-catalyzed intramolecular C-H insertion reaction of chiral alpha-diazo-beta-oxo ester 2 as a key step.

引用

页码：973 / 974

页数：2

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