An innovative zinc oxide-coated zeolite adsorbent for removal of humic acid

被引:66
|
作者
Wang, Lingling [1 ,2 ]
Han, Changseok [3 ]
Nadagouda, Mallikarjuna N. [4 ]
Dionysiou, Dionysios D. [2 ,5 ]
机构
[1] Quanzhou Normal Univ, Coll Chem Engn & Mat, Quanzhou 362000, Fujian, Peoples R China
[2] Univ Cincinnati, Engn Res Ctr 705, Environm Engn & Sci Program, Cincinnati, OH 45221 USA
[3] US EPA, ORD, NRMRL, STD,CPB, 26 W Martin Luther King Jr Dr, Cincinnati, OH 45268 USA
[4] US EPA, ORD, NRMRL, WSWRD,WQMB, 26 W Martin Luther King Jr Dr, Cincinnati, OH 45268 USA
[5] Univ Cyprus, Sch Engn, Nireas Int Water Res Ctr, POB 20537, CY-1678 Nicosia, Cyprus
关键词
Electrostatic interaction; Humic acid; Water treatment; Zeolite; Zinc oxide; Natural organic matter; NATURAL ORGANIC-MATTER; AQUEOUS-SOLUTION; ACTIVATED CARBON; ADSORPTION; WATER; IONS; CHARGE; MONTMORILLONITE; ULTRAFILTRATION; EQUILIBRIUM;
D O I
10.1016/j.jhazmat.2016.03.070
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Zinc oxide (ZnO)-coated zeolite adsorbents were developed by both nitric acid modification and Zn(NO3)(2)center dot 6H(2)O functionalization of zeolite 4A. The developed adsorbents were used for the removal of humic acid (HA) from aqueous solutions. The synthesized materials were characterized by porosimetry analysis, scanning electron microscopy, X-Ray diffraction analysis, and high resolution transmission electron microscopy. The maximum adsorption capacity of the adsorbents at 21 +/- 1 degrees C was about 60 mgCg(-1). The results showed that the positive charge density of ZnO-coated zeolite adsorbents was proportional to the amount of ZnO coated on zeolite and thus, ZnO-coated zeolite adsorbents exhibited a greater affinity for negatively charged ions. Furthermore, the adsorption capacity of ZnO-coated zeolite adsorbents increased markedly after acid modification. Adsorption experiments demonstrated ZnO-coated zeolite adsorbents possessed high adsorption capacity to remove HA from aqueous solutions mainly due
引用
收藏
页码:283 / 290
页数:8
相关论文
共 50 条
  • [21] Iron Oxide-Coated on Glass Fibers for Arsenic Removal
    Wang, Jinwen
    Li, Xuan
    Ince, Jeffrey Scott
    Yue, Zhongren
    Economy, James
    SEPARATION SCIENCE AND TECHNOLOGY, 2010, 45 (08) : 1058 - 1065
  • [22] Iron oxide-coated fibrous sorbents for arsenic removal
    Kumar, Arun
    Gurian, Patrick L.
    Bucciarelli-Tieger, Robin H.
    Mitchell-Blackwood, Jade
    JOURNAL AMERICAN WATER WORKS ASSOCIATION, 2008, 100 (04): : 151 - +
  • [23] ILLUSION OF TRACED FORGERY ON ZINC OXIDE-COATED PHOTOCOPY PAPER
    WALTERS, A
    FLYNN, WJ
    JOURNAL OF POLICE SCIENCE AND ADMINISTRATION, 1974, 2 (04): : 376 - 380
  • [24] Zero-valent iron and iron oxide-coated sand as a combination for removal of co-present chromate and arsenate from groundwater with humic acid
    Mak, Mark S. H.
    Rao, Pinhua
    Lo, Irene M. C.
    ENVIRONMENTAL POLLUTION, 2011, 159 (02) : 377 - 382
  • [25] MODELING SOLUBLE MANGANESE REMOVAL BY OXIDE-COATED FILTER MEDIA
    COFFEY, BM
    GALLAGHER, DL
    KNOCKE, WR
    JOURNAL OF ENVIRONMENTAL ENGINEERING-ASCE, 1993, 119 (04): : 679 - 694
  • [26] Layer structured graphite oxide as a novel adsorbent for humic acid removal from aqueous solution
    Hartono, Tri
    Wang, Shaobin
    Ma, Qing
    Zhu, Zhonghua
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 333 (01) : 114 - 119
  • [27] Zinc Oxide Nanoclusters Encapsulated in MFI Zeolite as a Highly Stable Adsorbent for the Ultradeep Removal of Hydrogen Sulfide
    Yu, Tao
    Zheng, Jinyu
    Su, Shikun
    Wang, Yundong
    Xu, Jianhong
    Liu, Zhendong
    JACS AU, 2024, 4 (03): : 985 - 991
  • [29] Arsenite removal by adsorption onto iron oxide-coated pumice and sepiolite
    Merve Dönmez Öztel
    Feryal Akbal
    Levent Altaş
    Environmental Earth Sciences, 2015, 73 : 4461 - 4471
  • [30] Removal of arsenic from ground water by iron oxide-coated sand
    Joshi, A
    Chaudhuri, M
    JOURNAL OF ENVIRONMENTAL ENGINEERING-ASCE, 1996, 122 (08): : 769 - 771