The effect of the inorganic nanomaterials on the UV-absorption, rheological and mechanical properties of the rapid prototyping epoxy-based composites

被引:24
作者
Wang, Lu [1 ]
Ni, Xiuyuan [1 ]
机构
[1] Fudan Univ, Dept Macromol Sci, State Key Lab Mol Engn Polymers, Shanghai 200433, Peoples R China
关键词
Nanocomposites; Rapid prototyping; Stereolithography; Digital light processing; Epoxy; Viscosity; Light absorption; Dental model; GLASS-TRANSITION TEMPERATURE; NANOCOMPOSITES; STEREOLITHOGRAPHY; TECHNOLOGIES; GRAPHENE; BEHAVIOR; FILLER; RESINS;
D O I
10.1007/s00289-016-1825-x
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We here report the photosensitive nanocomposites as the new rapid prototyping materials. The nanocomposites are prepared using the properly surface-modified sepiolite nanofibers, graphene oxide, TiO2 and SiO2 nanoparticles as the reinforcing fillers in the epoxy-based resin. These nanocomposites are investigated about the mechanical properties, viscosity and light absorption. By fitting the rheological test results into the Krieger-Dougherty equation, the influences of the different-shaped fillers on the material viscosity and the maximum packing fraction of the fillers are obtained. The extinction coefficients of the inorganic fillers are obtained using UV-Vis spectroscopy. The mechanical properties of the nanocomposites are improved due to the surface-modified inorganic fillers. It is found that the as-prepared materials are appropriate for stereolithography and digital light processing, with which we succeed in fabricating the dental model of high dimensional accuracy.
引用
收藏
页码:2063 / 2079
页数:17
相关论文
共 27 条
  • [1] The evolution of rapid prototyping in dentistry: a review
    Azari, Abbas
    Nikzad, Sakineh
    [J]. RAPID PROTOTYPING JOURNAL, 2009, 15 (03) : 216 - 225
  • [2] Silane treatment of magnetite filler and its effect on the properties of magnetite-filled epoxy thin-film composites
    Boon, M. S.
    Mariatti, M.
    [J]. POLYMER BULLETIN, 2014, 71 (12) : 3333 - 3346
  • [3] Conversion and temperature profiles during the photoinitiated polymerization of thick orthopaedic biomaterials
    Burdick, JA
    Peterson, AJ
    Anseth, KS
    [J]. BIOMATERIALS, 2001, 22 (13) : 1779 - 1786
  • [4] UV curable systems for tape casting
    Chartier, T
    Hinczewski, C
    Corbel, S
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1999, 19 (01) : 67 - 74
  • [5] A study of photomask correction method in area-forming rapid prototyping system
    Chiu, Shih-Hsuan
    Pong, Sheng-Hong
    Wu, Dien-Chi
    Lin, Chien-Hung
    [J]. RAPID PROTOTYPING JOURNAL, 2008, 14 (05) : 285 - 292
  • [6] Organically modified montmorillonite polymer nanocomposites for stereolithography building process
    Corcione, C. Esposito
    Striani, R.
    Montagna, F.
    Cannoletta, D.
    [J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 2015, 26 (01) : 92 - 98
  • [7] Nano-TiO2-modified photosensitive resin for RP
    Duan Yugang
    Zhou Yuan
    Tang Yiping
    Li Dichen
    [J]. RAPID PROTOTYPING JOURNAL, 2011, 17 (04) : 247 - 252
  • [8] Additive fabrication technologies applied to medicine and health care: a review
    Giannatsis, J.
    Dedoussis, V.
    [J]. INTERNATIONAL JOURNAL OF ADVANCED MANUFACTURING TECHNOLOGY, 2009, 40 (1-2) : 116 - 127
  • [9] Acrylic nanocomposite resins for use in stereolithography and structural light modulation based rapid prototyping and rapid manufacturing technologies
    Gurr, Matthias
    Hofmann, Daniel
    Ehm, Michael
    Thomann, Yi
    Kuebler, Rainer
    Muelhaupt, Rolf
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (16) : 2390 - 2397
  • [10] Additive manufacturing (AM) and nanotechnology: promises and challenges
    Ivanova, Olga
    Williams, Christopher
    Campbell, Thomas
    [J]. RAPID PROTOTYPING JOURNAL, 2013, 19 (05) : 353 - 364