Synthesis, characterization, and applications of fluorous resorcin[4]arenes

被引：10

作者：

Chu, Qianli ^{[1
]}

O'Neal, Kristi ^{[2
]}

Osipov, Maksim ^{[2
]}

Ngwendson, Julius N. ^{[1
]}

Geib, Steven J. ^{[2
]}

Weber, Stephen G. ^{[2
]}

Curran, Dennis P. ^{[2
]}

机构：

[1] Univ N Dakota, Dept Chem, Grand Forks, ND 58202 USA

[2] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2010年 / 34卷 / 12期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

PHASE SCREEN; EXTRACTION; ACIDS; RESORCINARENE; SEPARATION; EXECUTION; CHEMISTRY; ARYLATION; TRANSPORT; SOLVENTS;

D O I：

10.1039/c0nj00344a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three fluorous resorcin[4]arenes (1a-c) were synthesized and characterized for their potential application in separation science. A crystal structure of 1b confirmed its ring size and conformation. The fluorous resorcin[4] arenes are soluble in hybrid fluorous solvents. Preliminary studies demonstrated that 1a immobilized in a fluorous bulk membrane is capable of transporting tetramethylammonium cation from an aqueous source phase into an aqueous receiving phase.

引用

页码：2732 / 2734

页数：3

共 27 条

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