Sequence Stereoisomerism in Calixarene-Based Pseudo[3]rotaxanes

被引：42

作者：

Talotta, Carmen ^{[1
]}

Gaeta, Carmine ^{[1
]}

Pierro, Teresa ^{[1
]}

Neri, Placido ^{[1
]}

机构：

[1] Univ Salerno, Dipartimento Chim & Biol, I-84084 Salerno, Italy

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 08期

关键词：

ALPHA-CYCLODEXTRIN;

D O I：

10.1021/ol2005159

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two calix[6]arene directional wheels can be ordered in the right stereosequence by their through-the-annulus threading with a rationally designed bis(benzylalkylammonium) axle. These stereoisomeric pseudo[3]rotaxanes can be considered as a minimal "informational system" because the "written information" on the thread is transferred to a specific sequence stereoisomer.

引用

页码：2098 / 2101

页数：4