Phosphonates Meet Metal-Organic Frameworks: Towards CO2 Adsorption

被引：6
|
作者：
da Silva, Cleiser Thiago P. [1 ,2 ]
Howarth, Ashlee J. [1 ,3 ]
Rimoldi, Martino [1 ]
Islamoglu, Timur [1 ]
Rinaldi, Andrelson W. [2 ]
Hupp, Joseph T. [1 ]
机构：
[1] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA
[2] Univ Estadual Maringa, Lab Mat Chem & Sensors, Av Colombo 5790, BR-87020900 Maringa, PR, Brazil
[3] Concordia Univ, Dept Chem & Biochem, 7141 Sherbrooke St W, Montreal, PQ H4B 1R6, Canada
来源：
ISRAEL JOURNAL OF CHEMISTRY | 2018年 / 58卷 / 9-10期
基金：
美国国家科学基金会;
关键词：
metal-organic frameworks; porous phosphonates; carbon dioxide capture; zirconium-based MOFs; CARBON-DIOXIDE CAPTURE; CRYSTAL-STRUCTURE; PROTON CONDUCTIVITY; POROUS MATERIALS; PORE-SIZE; DESIGN; MOFS; STABILITY; PH; FUNCTIONALIZATION;
D O I：
10.1002/ijch.201800129
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Here we report a new highly microporous zirconium phosphonate material synthesized under solvothemal conditions. The specific Brunauer-Emmett-Teller (BET) surface area of the "unconventional metal-organic framework" (UMOF) is measured to be similar to 900 m(2)/g, after following an appropriate activation protocol. Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) shows that the material bears a free -OH functionality on the phosphonate linker that may interact with CO2. CO2 adsorption isotherms were collected and a measured heat of adsorption of 31 kJ/mol was obtained. In addition, adsorption isotherms of CO2, N-2, and CH4 at 298 K combined with Ideal Adsorbed Solution Theory (IAST) show that the material can be expected to display high selectivities for uptake of CO2 versus N-2 or CH4.
引用
收藏
页码：1164 / 1170
页数：7
相关论文
共 50 条
  • [41] Ab Initio Adsorption Isotherms for Molecules with Lateral Interactions: CO2 in Metal-Organic Frameworks
    Sillar, Kaido
    Kundu, Arpan
    Sauer, Joachim
    JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (23) : 12789 - 12799
  • [42] Interpenetrated metal-organic frameworks and their uptake of CO2 at relatively low pressures
    Yao, Qingxia
    Su, Jie
    Cheung, Ocean
    Liu, Qingling
    Hedin, Niklas
    Zou, Xiaodong
    JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (20) : 10345 - 10351
  • [43] Post-combustion CO2 capture with the HKUST-1 and MIL-101(Cr) metal-organic frameworks: Adsorption, separation and regeneration investigations
    Ye, Sheng
    Jiang, Xin
    Ruan, Lin-Wei
    Liu, Bei
    Wang, Yi-Min
    Zhu, Jun-Fa
    Qiu, Ling-Guang
    MICROPOROUS AND MESOPOROUS MATERIALS, 2013, 179 : 191 - 197
  • [44] Sustainable and scalable continuous synthesis of metal-organic frameworks for CO2 capture
    Chen, Yipei
    Wu, Tao
    GREENHOUSE GASES-SCIENCE AND TECHNOLOGY, 2023, 13 (03) : 409 - 420
  • [45] Screening the Effect of Water Vapour on Gas Adsorption Performance: Application to CO2 Capture from Flue Gas in Metal-Organic Frameworks
    Chanut, Nicolas
    Bourrelly, Sandrine
    Kuchta, Bogdan
    Serre, Christian
    Chang, Jong-San
    Wright, Paul A.
    Llewellyn, Philip L.
    CHEMSUSCHEM, 2017, 10 (07) : 1543 - 1553
  • [46] Metal-Organic Frameworks as a Platform for CO2 Capture and Chemical Processes: Adsorption, Membrane Separation, Catalytic-Conversion, and Electrochemical Reduction of CO2
    Elhenawy, Salma Ehab Mohamed
    Khraisheh, Majeda
    AlMomani, Fares
    Walker, Gavin
    CATALYSTS, 2020, 10 (11) : 1 - 33
  • [47] Application of metal-organic frameworks in CO2 hydrogenation
    Zhou C.
    Nan Y.-Y.
    Zha F.
    Tian H.-F.
    Tang X.-H.
    Chang Y.
    Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2021, 49 (10): : 1444 - 1457
  • [48] Computational exploration of metal-organic frameworks for CO2/CH4 separation via temperature swing adsorption
    Li, Zhengjie
    Xiao, Gang
    Yang, Qingyuan
    Xiao, Yuanlong
    Zhong, Chongli
    CHEMICAL ENGINEERING SCIENCE, 2014, 120 : 59 - 66
  • [49] BTC-based metal-organic frameworks: Correlation between relevant structural features and CO2 adsorption performances
    Gargiulo, Valentina
    Alfe, Michela
    Raganati, Federica
    Lisi, Luciana
    Chirone, Riccardo
    Ammendola, Paola
    FUEL, 2018, 222 : 319 - 326
  • [50] Selective adsorption of CO2/CH4 and CO2/N2 within a charged metal-organic framework
    Kong, Lidan
    Zou, Ruyi
    Bi, Wenzhu
    Zhong, Ruiqin
    Mu, Weijun
    Liu, Jia
    Han, Ray P. S.
    Zou, Ruqiang
    JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (42) : 17771 - 17778
12345