[B(3,5-C6H3Cl2)4]- as a Useful Anion for Organometallic Chemistry

被引：38

作者：

Chaplin, Adrian B. ^{[1
]}

Weller, Andrew S. ^{[1
]}

机构：

[1] Univ Oxford, Dept Chem, Inorgan Chem Labs, Oxford OX1 3QR, England

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 32期

基金：

英国工程与自然科学研究理事会;

关键词：

Rhodium; Boranes; Organometallic complexes; Weakly coordinating anions; Structure elucidation; WEAKLY COORDINATING ANIONS; X-RAY-DIFFRACTION; NONCOORDINATING ANIONS; OXIDATIVE ADDITION; COMPLEXES; ROUTE;

D O I：

10.1002/ejic.201000686

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We highlight the use of the robust [B(3,5 C6H3Cl2)(4)](-) anion m organometallic chemistry When partnered with organo metallic cations, compared with [BAr4F](-) it presents desirable solubility properties a lack of anion disorder in the solid state different coordinating properties with metal fragments and convenient metathetical routes for utilisation in synthesis

引用

页码：5124 / 5128

页数：5

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