Suppression of temperature hysteresis in negative thermal expansion compound BiNi1-xFexO3 and zero-thermal expansion composite

被引：64

作者：

Nabetani, K. ^{[1
]}

Muramatsu, Y. ^{[1
]}

Oka, K. ^{[1
,2
]}

Nakano, K. ^{[1
]}

Hojo, H. ^{[1
]}

Mizumaki, M. ^{[3
]}

Agui, A. ^{[4
]}

Higo, Y. ^{[3
]}

Hayashi, N. ^{[5
]}

Takano, M. ^{[5
]}

Azuma, M. ^{[1
]}

机构：

[1] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

[2] Chuo Univ, Fac Sci & Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1128551, Japan

[3] SPring 8, Japan Synchrotron Radiat Res Inst, Sayo, Hyogo 6795198, Japan

[4] Japan Atom Energy Agcy, Quantum Beam Sci Ctr, Sayo, Hyogo 6795148, Japan

[5] Kyoto Univ, Inst Integrated Cell Mat Sci, Kyoto 6068501, Japan

来源：

APPLIED PHYSICS LETTERS | 2015年 / 106卷 / 06期

关键词：

CHARGE-TRANSFER; PEROVSKITE; BINIO3;

D O I：

10.1063/1.4908258

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Negative thermal expansion (NTE) of BiNi1-xFexO3 is investigated. All x = 0.05, 0.075, 0.10, and 0.15 samples shows large NTE with the coefficient of linear thermal expansion (CTE) alpha(L) exceeding -150 ppm K-1 induced by charge transfer between Bi5+ and Ni2+ in the controlled temperature range near room temperature. Compared with Bi(1-x)Ln(x)NiO(3) (Ln: rare-earth elements), the thermal hysteresis that causes a problem for practical application is suppressed because random distribution of Fe in the Ni site changes the first order transition to second order-like transition. The CTE of BiNi0.85Fe0.15O3 reaches -187 ppm K-1 and it is demonstrated that 18 vol. % addition of the present compound compensates for the thermal expansion of epoxy resin. (C) 2015 AIP Publishing LLC.

引用

页数：5

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