Hyperbranched polyester poly[3-(morpholin-4-yl)propionates] and their copper(II) complexes

被引：5

作者：

Gataulina, A. R. ^{[1
]}

Khasanova, E. M. ^{[1
]}

Basalaev, A. S. ^{[1
]}

Ulakhovich, N. A. ^{[1
]}

Kutyrev, G. A. ^{[2
]}

Yurtaeva, S. V. ^{[3
]}

Kutyreva, M. P. ^{[1
]}

机构：

[1] Kazan Volga Reg Fed Univ, Butlerov Inst Chem, Ul Kremlevskaya 18, Kazan 420008, Tatarstan, Russia

[2] Kazan Natl Res Technol Univ, Kazan, Tatarstan, Russia

[3] Russian Acad Sci, Zavoiskii Phys Tech Inst, Kazan, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2017年 / 87卷 / 09期

关键词：

hyperbranched polyester poly[3-(morpholin-4-yl)propionates; copper(II) complexes; ionization; complex formation; electronic absorption spectroscopy; SUBSTITUTED MORPHOLINE DERIVATIVES; SPECTRAL CHARACTERISTICS; METAL-COMPLEXES; BINARY-SYSTEMS; ACIDS; POLYOLS;

D O I：

10.1134/S1070363217090158

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel polydentate ligands on the basis of second- and third-generation hyperbranched polyesters containing terminal poly[3-(morpholin-4-yl)propionate] groups and their 6 : 1 and 13 : 1 polynuclear copper(II) complexes were synthesized. The degree of functionalization of the polyesters with morpholine increases in going from the second (56%) to third generation (68%). According to IR and electronic spectroscopy data, each coordination entity in the complexes is an isolated paramagnetic center of the formula CuN(2)O(2)Solv(2) (Solv = H2O, DMSO).

引用

页码：1995 / 2005

页数：11

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