A High-Performance Direct Methanol Fuel Cell Technology Enabled by Mediating High-Concentration Methanol through a Graphene Aerogel

被引：41

作者：

Liu, Xiaoteng ^{[1
]}

Xi, Jiabin ^{[2
]}

Xu, Ben Bin ^{[1
]}

Fang, Bo ^{[2
]}

Wang, Yucheng ^{[1
]}

Bayati, Maryam ^{[3
]}

Scott, Keith ^{[3
]}

Gao, Chao ^{[2
]}

机构：

[1] Northumbria Univ, Dept Mech & Construct Engn, Fac Engn & Environm, Newcastle Upon Tyne NE1 8ST, Tyne & Wear, England

[2] Zhejiang Univ, MOE Key Lab Macromol Synth & Functionalizat, Dept Polymer Sci & Engn, Key Lab Adsorpt & Separat Mat & Technol Zhejiang, 38 Zheda Rd, Hangzhou 310027, Peoples R China

[3] Newcastle Univ, Sch Chem Engn & Adv Mat, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

SMALL METHODS | 2018年 / 2卷 / 10期

基金：

英国工程与自然科学研究理事会; 国家重点研发计划;

关键词：

direct methanol fuel cells; fuel storage; graphene aerogels; high methanol concentration; mass power density; LITHIUM-ION BATTERIES; ELECTROCATALYTIC ACTIVITY; OIL; CHALLENGES; ULTRALIGHT; CROSSOVER; CATALYST; ROBUST;

D O I：

10.1002/smtd.201800138

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A facile methodology to fabricate graphene aerogel (GA), and its application in a direct methanol fuel cell (DMFC), is demonstrated for the first time. A new GADMFC design is proposed by using GA to replace two main components within the DMFCthe gas-diffusion layer and the flow field plate. The results indicate a 24.95 mW cm(-2) maximum power density of air polarization is obtained at 25 degrees C. The membrane electrolyte assembly has a 63.8% mass reduction compared to an ordinary one, which induced 3 times higher mass power density. Benefiting from its excellent organic solvent absorbency, the methanol crossover effect is dramatically suppressed while using 12 m methanol, therefore, a higher concentration or even pure methanol can be refilled into the fuel cell. Due to the excellent fuel-storage function of the GA, the methanol cartridge and complicated fuel circulation system in the DMFC can be eliminated, which can reduce the manufacturing cost for DMFCs. It is expected this research will promote the application of GA in fuel-cell applications, as well as shed light on the novel fuel-cell technology to address future energy challenges.

引用

页数：6

共 38 条

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