Synthesis of 3-Substituted Derivatives of 2,2,6,6-Tetramethylpiperidine-N- alkoxyamine Ethers: Novel Alkoxyamine Building Blocks

被引：3

作者：

Fischer, Walter ^{[1
]}

Basbas, Abdel-Ilah ^{[1
]}

Schoening, Kai-Uwe ^{[1
]}

Hauck, Stefan ^{[2
]}

机构：

[1] BASF Schweiz AG, CH-4002 Basel, Switzerland

[2] Galata Chem GmbH, D-68623 Lampertheim, Germany

来源：

SYNTHESIS-STUTTGART | 2010年 / 22期

关键词：

N-alkoxyamines; radical reaction; piperidines; peroxides; TEMPO derivatives; DYNAMIC KINETIC RESOLUTION; ENANTIOSELECTIVE SYNTHESIS; CYCLOADDITION REACTIONS; KETONES; DESYMMETRIZATION; POLYMERIZATION; PIPERIDINES; INHIBITORS; ENAMINES; RADICALS;

D O I：

10.1055/s-0030-1258255

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Michael addition of 4-oxo-TMP-alkoxyamine-derived Schiff bases to acrylates provides a convenient way to obtain a variety of novel and versatile alkoxyamine building blocks.

引用

页码：3873 / 3878

页数：6

共 39 条

[1] FUNCTIONALIZED CHLOROENAMINES IN AMINOCYCLOPROPANE SYNTHESIS .1. BICYCLIC AND PENTACYCLIC LACTAMS FROM CARBAMOYLATED CHLOROENAMINES [J].