Neutral and cationic palladium(II) and platinum(II) complexes of 2,2′-dipyridylamine with saccharinate: Syntheses, spectroscopic, structural, fluorescent and thermal studies

被引：43

作者：

Guney, Emel ^{[1
]}

Yilmaz, Veysel T. ^{[1
]}

Buyukgungor, Orhan ^{[2
]}

机构：

[1] Uludag Univ, Fac Arts & Sci, Dept Chem, TR-16059 Bursa, Turkey

[2] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Phys, TR-55139 Samsun, Turkey

来源：

INORGANICA CHIMICA ACTA | 2010年 / 363卷 / 11期

关键词：

Saccharinate; 2,2 '-Dipyridylamine; Palladium(II); Platinum(II); Crystal structures; CRYSTAL-STRUCTURE; DNA-BINDING; METAL-COMPLEXES; COPPER(II); LIGANDS; DI-2-PYRIDYLAMINE; DIPYRIDYLAMINE; COORDINATION;

D O I：

10.1016/j.ica.2010.03.077

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four palladium(II) and platinum(II) complexes of 2,2 '-dipyridylamine (dpya) with saccharinate (sac), cis[Pd(dpya)(sac)(2)]center dot H(2)O (1), cis-[Pt(dpya)(sac)(2)]center dot H(2)O (2), [Pd(dpya)(2)](sac)(2)center dot 2H(2)O (3) and [Pt(dpya)(2)] (sac)(2)center dot 2H(2)O (4), have been synthesized and characterized by elemental analysis, IR, NMR, TG-DTA and X-ray diffraction. In 1 and 2, the metal ions are coordinated by two N-bonded sac ligands, and two nitrogen atoms of dpya, resulting in a neutral square- planar coordination sphere, while in 3 and 4, the metal ions are coordinated by two dpya ligands to generate square-planar cationic species, which are stabilized by two sac counter-ions. The mononuclear species of 1 and 2 interact each other through weak intermolecular N-H center dot center dot center dot O, C-H center dot center dot center dot O and pi center dot center dot center dot pi interactions to form a three-dimensional network, while the ions of 3 and 4 are connected by N-H center dot center dot center dot N and OW-H center dot center dot center dot O hydrogen bonds into one-dimensional chains. On heating at 250 degrees C, the solid cationic complexes of 3 and 4 convert to corresponding anhydrous neutral complexes of 1 and 2 after elimination of a dpya ligand. In addition, all complexes 1-4 are luminescent at room temperature and their emissions seem to be attributed to the MLCT fluorescence. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：2416 / 2424

页数：9

共 33 条

[1] Interaction of copper(II) and palladium(II) with linked 2,2′-dipyridylamine derivatives:: Synthetic and structural studies [J].

Antonioli, Bianca ;

Bray, David J. ;

Clegg, Jack K. ;

Gloe, Kerstin ;

Gloe, Karsten ;

Jaeger, Anne ;

Jolliffe, Katrina A. ;

Kataeva, Olga ;

Lindoy, Leonard F. ;

Steel, Peter J. ;

Sumby, Christopher J. ;

Wenzel, Marco .

POLYHEDRON, 2008, 27 (13) :2889-2898

[2] Metal complexes of saccharin [J].

Baran, Enrique J. ;

Yilmaz, Veysel T. .

COORDINATION CHEMISTRY REVIEWS, 2006, 250 (15-16) :1980-1999

[3] Synthesis, structure and properties of [Zn(dpa)(N3)2] and [Zn(dpa)(N3)(NO3)]2 (dpa=2,2'-dipyridylamine):: composition tailored architectures [J].

Bose, D ;

Rahaman, SH ;

Mostafa, G ;

Walsh, RDB ;

Zaworotko, MJ ;

Ghosh, BK .

POLYHEDRON, 2004, 23 (04) :545-552

[4] The Mn(II)-2,2′-dipyridylamine-pseudohalide system:: Synthesis, crystal structure and luminescence behaviour of [Mn(dpa)2(X)2]•H2O and [Mn(dpa)2(X)(OH2)]ClO4 (dpa=2,2′-dipyridylamine;: X = N3-NCO-) [J].

Bose, D ;

Mostafa, G ;

Fun, HK ;

Ghosh, BK .

POLYHEDRON, 2005, 24 (06) :747-758

[5]

Burgos M, 2003, EUR J INORG CHEM, P2170

[6] Copper(II)nitrito complexes with 2,2′-dipyridylamine.: Crystal structures of the [(acetato)(2,2′-dipyridylamine)(nitrito-O,O′)copper(II)] and [(2,2′-dipyridylamine) (nitrito-O,O′)(μ-nitrito-O)copper(II)]2•2(acetonitrile) [J].

Camus, A ;

Marsich, N ;

Lanfredi, AMM ;

Ugozzoli, F ;

Massera, C .

INORGANICA CHIMICA ACTA, 2000, 309 (1-2) :1-9

[7] Synthesis and X-ray structure of the dinuclear platinum(II) complex with saccharin {K[Pt(sac)3(H2O)] • H2O}2:: Studies on its antiproliferative activity in aqueous solution [J].

Cavicchioli, Mauricio ;

Massabni, Antonio Carlos ;

Castellano, Eduardo Ernesto ;

Sabeh, Lilian P. B. ;

Costa-Neto, Claudio M. .

INORGANICA CHIMICA ACTA, 2007, 360 (09) :3055-3060

[8] Synthesis and spectroscopic studies of 2,2'-dipyridylamine complexes of La(III), Ce(III), Pr(III), Th(IV), UO2(VI) and a peroxo derivative of UO2(VI) [J].

Chattopadhyay, P ;

Sinha, C .

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1997, 27 (07) :997-1007

[9] Symmetrical and unsymmetrical compounds having a linear Co-3(6+) chain ligated by a spiral set of dipyridyl anions [J].

Cotton, FA ;

Daniels, LM ;

Jordan, GT ;

Murillo, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (43) :10377-10381

[10] Two products from the reaction of dipyridylamine with [Cu(sac)2(H2O)4]•2H2O, including the first example of a mononuclear transition metal complex with both N- and O-bonded saccharinate ligands [J].

Deng, RMK ;

Dillon, KB ;

Goeta, AE ;

Mapolelo, M .

INORGANICA CHIMICA ACTA, 2001, 315 (02) :245-248

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