Microstructure of 1,2-trans- and 1,4-trans-poly(penta-1,3-dienes)

被引：4

作者：

Rozentsvet, V. A. ^{[1
]}

Khachaturov, A. S. ^{[2
]}

Ivanova, V. P. ^{[2
]}

机构：

[1] Russian Acad Sci, Volga Basin Ecol Inst, Tolyatti 445003, Russia

[2] SV Lebedev Synthet Rubber Res Inst, St Petersburg 198035, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2007年 / 56卷 / 06期

关键词：

poly(penta-1,3-diene); polymers; hydrogenation; microstructure; C-13 NMR spectroscopy;

D O I：

10.1007/s11172-007-0175-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Microstructures of 1,2-trans- and 1,4-trans-poly(penta-1,3-dienes) synthesized using different catalysts were determined by high resolution C-13 NMR spectroscopy. The content of dyad combinations of the 1,4-and 1,2-structures was quantitatively determined in hydrogenated poly(penta-1,3-dienes) from the ratio of intensities of the characteristic signals of the carbon atoms of the methylene groups in the C-13 NMR spectra.

引用

页码：1156 / 1161

页数：6

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