Bio-functionalization of metal-organic frameworks by covalent protein conjugation

被引：216

作者：

Jung, Suhyun ^{[2
]}

Kim, Youngmee ^{[3
]}

Kim, Sung-Jin ^{[3
]}

Kwon, Tae-Hwan ^{[1
,4
]}

Huh, Seong ^{[1
,4
]}

Park, Seongsoon ^{[2
]}

机构：

[1] Hankuk Univ Foreign Studies, Dept Chem, Yongin 449791, South Korea

[2] Sungshin Womens Univ, Dept Chem, Ctr NanoBio Appl Technol, Inst Basic Sci, Seoul 136742, South Korea

[3] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea

[4] Hankuk Univ Foreign Studies, Prot Res Ctr Bioind, Yongin 449791, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 10期

关键词：

POSTSYNTHETIC MODIFICATION; CANDIDA-ANTARCTICA; HYDROGEN STORAGE; ROOM-TEMPERATURE; CATALYSIS; DESIGN;

D O I：

10.1039/c0cc03288c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bioconjugation of functional proteins onto metal-organic frameworks (MOFs) has been achieved using activation of pendent linking groups of the organic linkers on the surface of MOFs. Fluorescent microscopy revealed successful conjugation of an enhanced fluorescent protein onto MOFs. In addition, Candida-antarctica-lipase-B-conjugated MOFs showed no loss of enantioselectivity and activity in transesterification of (+/-)-1-phenylethanol.

引用

页码：2904 / 2906

页数：3

共 32 条

[1] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].

Banerjee, Rahul ;

Phan, Anh ;

Wang, Bo ;

Knobler, Carolyn ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2008, 319 (5865) :939-943

[2] Post-Synthetic Modification of Tagged Metal-Organic Frameworks [J].

Burrows, Andrew D. ;

Frost, Christopher G. ;

Mahon, Mary F. ;

Richardson, Christopher .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (44) :8482-8486

[3] Chemical modification of a bridging ligand inside a metal-organic framework while maintaining the 3D structure [J].

Costa, Jose Sanchez ;

Gamez, Patrick ;

Black, Cory A. ;

Roubeau, Olivier ;

Teat, Simon J. ;

Reedijk, Jan .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (10) :1551-1554

[4] Investigation of the Yamaguchi esterification mechanism. Synthesis of a Lux-S enzyme inhibitor using an improved esterification method [J].

Dhimitruka, H ;

SantaLucia, J .

ORGANIC LETTERS, 2006, 8 (01) :47-50

[5] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[6] Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M(OH)(O2C-C6H4-CO2) (M = Al3+, Cr3+), MIL-53 [J].

Férey, G ;

Latroche, M ;

Serre, C ;

Millange, F ;

Loiseau, T ;

Percheron-Guégan, A .

CHEMICAL COMMUNICATIONS, 2003, (24) :2976-2977

[7] PREPARATION, CLATHRATION ABILITY, AND CATALYSIS OF A 2-DIMENSIONAL SQUARE NETWORK MATERIAL COMPOSED OF CADMIUM(II) AND 4,4'-BIPYRIDINE [J].

FUJITA, M ;

KWON, YJ ;

WASHIZU, S ;

OGURA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :1151-1152

[8] Covalent surface modification of a metal-organic framework: selective surface engineering via CuI-catalyzed Huisgen cycloaddition [J].

Gadzikwa, Tendai ;

Lu, Guang ;

Stern, Charlotte L. ;

Wilson, Scott R. ;

Hupp, Joseph T. ;

Nguyen, SonBinh T. .

CHEMICAL COMMUNICATIONS, 2008, (43) :5493-5495

[9] DABCO-functionalized metal-organic framework bearing a C2h-symmetric terphenyl dicarboxylate linker [J].

Gu, Ja-Min ;

Kwon, Tae-Hwan ;

Park, Ji-Hyun ;

Huh, Seong .

DALTON TRANSACTIONS, 2010, 39 (24) :5608-5610

[10] Two-dimensional metal-organic frameworks with blue luminescence [J].

Huh, Seong ;

Jung, Suhyun ;

Kim, Youngmee ;

Kim, Sung-Jin ;

Park, Seongsoon .

DALTON TRANSACTIONS, 2010, 39 (05) :1261-1265

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