Copper porphyrin-catalyzed cross dehydrogenative coupling of alkanes with carboxylic acids: Esterification and decarboxylation dual pathway

被引：8
作者：
Chen, Xiao-Yan [1 ]
Yang, Shuang [1 ]
Ren, Bao-Ping [1 ]
Shi, Lei [2 ]
Lin, Dong-Zi [3 ]
Zhang, Hao [1 ]
Liu, Hai-Yang [1 ]
机构：
[1] South China Univ Technol, Dept Chem, Key Lab Fuel Cell Technol Guangdong Prov, Guangzhou 510641, Peoples R China
[2] Guangdong Univ Educ, Dept Chem, Guangzhou 510303, Peoples R China
[3] Foshan Forth Peoples Hosp, Dept Lab Med, Foshan 528041, Peoples R China
来源：
TETRAHEDRON | 2021年 / 96卷
基金：
中国国家自然科学基金;
关键词：
Cross dehydrogenative coupling; Carboxylic acids; Alkanes; Porphyrin; Copper; C-O BOND; ALLYLIC ESTERS; CYCLIC ETHERS; FACILE ACCESS; C(SP(3))-H; ACTIVATION; INTERMEDIATE; CYCLOALKANES; COMPLEX; OLEFINS;
D O I：
10.1016/j.tet.2021.132377
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A dual-functional copper porphyrin-catalyzed cross dehydrogenative coupling (CDC) of carboxylic acids with alkanes was reported firstly. The reaction gives allylic esters or alkylalkenes depending on the carboxylic acid substrates. Copper porphyrin catalyzed CDC method has the superiority of short reaction time, good functional group tolerance, base and solvent free, producing target products in an atom economic manner. (c) 2021 Elsevier Ltd. All rights reserved.
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页数：9
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