trans-Diaquadichlorooxovanadium(IV) bis[2-(2-pyridylamino)pyridinium] dichloride

被引：3

作者：

Hartung, J

Schmidt, P

Svoboda, I

Fuess, H

机构：

[1] Univ Kaiserslautern, Fachbereich Chem, D-6763 Kaiserslautern, Germany

[2] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

[3] Tech Univ Darmstadt, Strukturforsch, FB11 Mat & Geowissensch, D-64287 Darmstadt, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805016843

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The neutral complex trans-[VOCl2(H2O)(2)] co-crystallizes with di-2-pyridylamine hydrochloride to provide the title compound, (C10H10N3)(2)[VCl2O(H2O)(2)]Cl-2. The V- bound aqua ligands form two hydrogen bonds each. The amine functionality of the 2-(2-pyridylamino) pyridinium cation participates as a monovalent donor in the hydrogen bonding. In both instances, interstitial Cl- ions serve as hydrogen-bond acceptors. The three hydrogen bonds that are formed per anion give rise to one-dimensional chains along [100].

引用

页码：M1253 / M1255

页数：3

共 11 条

[1] MOLECULAR AND CRYSTAL-STRUCTURES OF TRANS-[VOCL2(H2O)2] HYDROGEN-BONDED ADDUCTS WITH 15-CROWN-5 AND BENZO-15-CROWN-5 ETHER [J].