Preparation of a Water-Based Lubricant from Lignocellulosic Biomass and Its Tribological Properties

被引：24

作者：

Ji, Hairui ^{[1
]}

Zhang, Xu ^{[1
]}

Tan, Tianwei ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, Natl Energy R&D Ctr Biorefinery, Coll Life Sci & Technol, Beijing 100029, Peoples R China

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2017年 / 56卷 / 27期

关键词：

OIL-BASED LUBRICANTS; LEVULINIC ACID; METHYL OLEATE; TEMPERATURE; BIOLUBRICANT; OPTIMIZATION; BEHAVIORS; ADDITIVES; OXIDATION; MIXTURES;

D O I：

10.1021/acs.iecr.7b01665

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Lignocellulosic biomass is considered as a major feedstock to produce value-added renewable chemicals. In this study, a new water-based lubricant was prepared using biomass derived levulinic acid (LA) and polyols such as ethylene glycol and glycerol. The products were separated by rotary film molecular distillation and characterized by '14 NMR and mass spectrometry. Lubricant properties such as kinematic viscosity, pour, cloud, and flash points, copper strip corrosion, and volatility at 120 degrees C were evaluated according to standard ASTM methods. Furthermore, the hydrolytic stability and tribological properties of the products were tested for water-based lubricants. The results indicated that glycerol ester of levulinic acid (LAGLE) exhibited superior lubricant properties, strong resistance to hydrolytic degradation, and excellent antiwear performance, implying that the biomass-derived LAGLF, was a potential water-based lubricant.

引用

页码：7858 / 7864

页数：7

共 37 条

[1] Synthesis and characterization of new esters of oleic acid and glycerol analogues as potential lubricants
Cavalcante, Igor Marques
Rocha, Natalia R. de C.
Maier, Martin E.
de Lima, Ana Paula Dantas
Andrade Neto, Davino M.
de Brito, Debora Hellen A.
Petzhold, Cesar L.
Schanz, Maria Telma G. F.
Ricardo, Nagila M. P. S.
[J]. INDUSTRIAL CROPS AND PRODUCTS, 2014, 62 : 453 - 459
[2] Delidovich I, 2014, ENERG ENVIRON SCI, V7, P2803, DOI [10.1039/C4EE01067A, 10.1039/c4ee01067a]
[3] Oxidation and low temperature stability of vegetable oil-based lubricants
Erhan, Sevim Z.
Sharma, Brajendra K.
Perez, Joseph M.
[J]. INDUSTRIAL CROPS AND PRODUCTS, 2006, 24 (03) : 292 - 299
[4] Tribological properties of aqueous solution of imidazoline borates
Gao, YJ
Jing, YS
Zhang, ZJ
Chen, GX
Xue, QJ
[J]. WEAR, 2002, 253 (5-6) : 576 - 578
[5] Process Pathways Optimization for a Lignocellulosic Biorefinery Producing Levulinic Acid, Succinic Acid, and Ethanol
Giuliano, Aristide
Cerulli, Raffaele
Poletto, Massimo
Raiconi, Giancarlo
Barletta, Diego
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2016, 55 (40) : 10699 - 10717
[6] Enzymatic synthesis of rapeseed oil-based lubricants
Gryglewicz, Stanislaw
Muszynski, Marcin
Nowicki, Janusz
[J]. INDUSTRIAL CROPS AND PRODUCTS, 2013, 45 : 25 - 29
[7] Full Film, Boundary Lubrication and Tribochemistry in Steel Circular Contacts Lubricated with Glycerol
Habchi, W.
Matta, C.
Joly-Pottuz, L.
De Barros, M. I.
Martin, J. M.
Vergne, P.
[J]. TRIBOLOGY LETTERS, 2011, 42 (03) : 351 - 358
[8] Production of levulinic acid from glucosamine by dilute-acid catalyzed hydrothermal process
Jeong, Gwi-Taek
[J]. INDUSTRIAL CROPS AND PRODUCTS, 2014, 62 : 77 - 83
[9] Emulsions containing vegetable oils for cutting fluid application
John, J
Bhattacharya, M
Raynor, PC
[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2004, 237 (1-3) : 141 - 150
[10] Tribological properties of monolayer graphene oxide sheets as water-based lubricant additives
Kinoshita, Hiroshi
Nishina, Yuta
Alias, Aidil Azli
Fujii, Masahiro
[J]. CARBON, 2014, 66 : 720 - 723

← 1 2 3 4 →