A [2]Rotaxane Flip Switch Driven by Coordination Geometry

被引：72

作者：

Davidson, Gregory J. E. ^{[1
]}

Sharma, Sapna ^{[1
]}

Loeb, Stephen J. ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 29期

基金：

加拿大自然科学与工程研究理事会;

关键词：

crown ethers; molecular machines; pi interactions; rotaxanes; supramolecular chemistry; 1,2-BIS(PYRIDINIUM)ETHANE AXLES; MOLECULAR SHUTTLE; BINDING-SITES; ETHER; COMPLEXES; ROTAXANE; RING; TERPYRIDINE; LIGANDS; POLYROTAXANES;

D O I：

10.1002/anie.201001486

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) The carrot Is better than the stick! Changes in the metal coordination geometry of the capping group in a [2]rotaxane ligand results in molecular switching by reorienting a trapped macrocyclic component (see picture). Switching was successfully initiated wher the metal coordination site was made more attractive (square planar), but not when the metal coordination site was made less attractive (octahedral). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, weinheim.

引用

页码：4938 / 4942

页数：5

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