Liquid-crystalline assembly from rigid wedge-flexible coil diblock molecules

被引:51
作者
Kim, JK
Hong, MK
Ahn, JH
Lee, M
机构
[1] Yonsei Univ, Ctr Supramol Nanoassembly, Seoul 120749, South Korea
[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
关键词
liquid crystals; nanostructures; polymers; self-assembly; supramolecular chemistry;
D O I
10.1002/anie.200461623
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Shape sorting: The incorporation of a flexible coil of variable length into a rigid wedge-shaped building block leads to the spontaneous formation of a rich variety of supramolecular structures. These include a bilayer lamellar structure with in-plane hexagonally ordered perforations (see picture, R = (CH2)13CH3).
引用
收藏
页码:328 / 332
页数:5
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