Quantitative measurement of ethanol distribution over fractions of ethanol-gasoline fuel

被引：65

作者：

Balabin, Roman M. ^{[1
]}

Syunyaev, Rustem Z. ^{[1
]}

Karpov, Sergey A. ^{[1
]}

机构：

[1] Gubkin Russian State Univ Oil & Gas, Moscow 119991, Russia

来源：

ENERGY & FUELS | 2007年 / 21卷 / 04期

关键词：

D O I：

10.1021/ef070081l

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

In this paper, we discuss the distribution of ethanol over fractions of alcohol-gasoline fuel. For the first time, quantitative data of ethanol distribution over fractions of ethanol-gasoline fuel have been obtained by the infrared (IR) spectroscopy method. Ethanol is found to nonuniformly distribute itself among gasoline fractions (thus, conclusions of earlier published works have been numerically confirmed). The form of ethanol distribution over fractions is found to be Gaussian-like. We found out that ethanol is concentrated in '' light '' ethanol-gasoline fractions and that it is almost completely absent in '' heavy '' ones (with a boiling point over 90 degrees C). The main part of ethanol (similar to 97% v/v) is found to form azeotropes-the reason for the fuel's high volatility.

引用

页码：2460 / 2465

页数：6

共 13 条

[1]

*ASTM INT, 481504 ASTM D

[2]

*ASTM INT, 584501 ASTM D

[3] Molar enthalpy of vaporization of ethanol-gasoline mixtures and their colloid state [J].

Balabin, Roman M. ;

Syunyaev, Rustem Z. ;

Karpov, Sergey A. .

FUEL, 2007, 86 (03) :323-327

[4]

CLARKE LJ, 2003, INTRO BIOFUELS GASOL

[5]

*COMM ENV NAT RES, 1997, INT ASS OXYG FUELS

[6] Effect of additives on the antiknock properties and Reid vapor pressure of gasoline [J].

da Silva, R ;

Cataluña, R ;

de Menezes, EW ;

Samios, D ;

Piatnicki, CMS .

FUEL, 2005, 84 (7-8) :951-959

[7] Analysis of gasolines by FT-IR spectroscopy [J].

Fodor, GE ;

Kohl, KB ;

Mason, RL .

ANALYTICAL CHEMISTRY, 1996, 68 (01) :23-30

[8]

FRENCH R, 2005, FLUID PHASE EQUILIBR, V27, P228

[9]

Lide D.R., 2005, CRC Handbook of Chemistry and Physics, DOI DOI 10.5860/CHOICE.41-4368

[10] Real-time monitoring of distillations by near-infrared spectroscopy [J].

Pasquini, C ;

Scafi, SHF .

ANALYTICAL CHEMISTRY, 2003, 75 (10) :2270-2275

← 1 2 →