Surface-modified polyethylene separator with hydrophilic property for enhancing the electrochemical performance of lithium-ion battery

被引：27
|
作者：
Ahn, Yong-keon [1 ]
Kwon, Yong Kab [1 ]
Kim, Ki Jae [1 ]
机构：
[1] Konkuk Univ, Dept Energy Engn, 120 Neungdong Ro, Seoul 05029, South Korea
来源：
INTERNATIONAL JOURNAL OF ENERGY RESEARCH | 2020年 / 44卷 / 08期
基金：
新加坡国家研究基金会;
关键词：
ammonium persulfate; hydrophilic; lithium-ion battery; polyolefin; separator; surface treatment; MEMBRANE; POLYPROPYLENE; ELECTROLYTES; TRANSPORT; OXIDATION; POWER;
D O I：
10.1002/er.5401
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The suggested surface treatment using ammonium persulfate (APS) successfully introduces hydrophilic functional groups onto the microporous structure of the polyethylene (PE) separators, leading to a high affinity toward polar liquid electrolytes without degrading the intrinsic physical properties of the separator. This improves the lithium-ion migration and ionic conductivity of the APS-treated separator, affording a stable cycle performance (92.5% at 90th cycle) and significantly improved rate capability (87.5% at 3 C).
引用
收藏
页码：6651 / 6659
页数：9
相关论文
共 50 条
  • [1] Surface-Modified Membrane as A Separator for Lithium-Ion Polymer Battery
    Kim, Jun Young
    Lim, Dae Young
    ENERGIES, 2010, 3 (04) : 866 - 885
  • [2] Plasma-modified polyethylene membrane as a separator for lithium-ion polymer battery
    Kim, Jun Young
    Lee, Yongbeom
    Lim, Dae Young
    ELECTROCHIMICA ACTA, 2009, 54 (14) : 3714 - 3719
  • [3] Surface-modified polyethylene separator via oxygen plasma treatment for lithium ion battery
    Jin, So Yeon
    Manuel, James
    Zhao, Xiaohui
    Park, Won Ho
    Ahn, Jou-Hyeon
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2017, 45 : 15 - 21
  • [4] Enhanced electrochemical performance of nanoparticle coated polyethylene separator surface for lithium-ion batteries
    Sivaprakash, Prabhavathy
    Sen, P. K.
    Sivaprakash, S.
    MATERIALS RESEARCH EXPRESS, 2014, 1 (04):
  • [5] Surface-modified electrospun polyacrylonitrile nano-membrane for a lithium-ion battery separator based on phase separation mechanism
    Dong, Ting
    Ul Arifeen, Waqas
    Choi, Jungwook
    Yoo, Kisoo
    Ko, Taejo
    CHEMICAL ENGINEERING JOURNAL, 2020, 398 (398)
  • [6] Surface-Modified Tin Nanoparticles and Their Electrochemical Performance in Lithium Ion Battery Cells
    Riedel, Olga
    Duettmann, Anke
    Duehnen, Simon
    Kony-Olesiak, Joanna
    Gutsche, Christian
    Parisi, Juergen
    Winter, Martin
    Knipper, Martin
    Placke, Tobias
    ACS APPLIED NANO MATERIALS, 2019, 2 (06) : 3577 - 3589
  • [7] Polyethylene separator grafting with polar monomer for enhancing the lithium-ion transport property
    Sheng, Lei
    Song, Li
    Gong, Hao
    Pan, Junjie
    Bai, Yaozong
    Song, Shangjun
    Liu, Gaojun
    Wang, Tao
    Huang, Xianli
    He, Jianping
    JOURNAL OF POWER SOURCES, 2020, 479
  • [8] Functionalized γ-Boehmite Covalent Grafting Modified Polyethylene for Lithium-Ion Battery Separator
    Man, Yuanxin
    Nan, Hui
    Ma, Jianzhe
    Li, Zhike
    Zhou, Jingyuan
    Wang, Xianlan
    Li, Heqi
    Xue, Caihong
    Yang, Yongchun
    MATERIALS, 2024, 17 (09)
  • [9] Preparation of hydrophilic polyethylene/methylcellulose blend microporous membranes for separator of lithium-ion batteries
    Liao, Haiyang
    Hong, Haoqun
    Zhang, Haiyan
    Li, Zhenghui
    JOURNAL OF MEMBRANE SCIENCE, 2016, 498 : 147 - 157
  • [10] Electrospun organically modified sepiolite/PVDF coating on polypropylene separator to improve electrochemical performance of lithium-ion battery
    Sun, Xianli
    Xu, Jiahao
    Zhi, Xiaoke
    Zhang, Jingpeng
    Hou, Kangwei
    Bian, Yuhan
    Li, Xiaolin
    Wang, Li
    Liang, Guangchuan
    EXPRESS POLYMER LETTERS, 2024, 18 (06): : 575 - 591
12345