Novel Lignin-Derived Water-Soluble Binder for Micro Silicon Anode in Lithium-Ion Batteries

被引:88
|
作者
Luo, Chao [1 ]
Du, Leilei [1 ]
Wu, Wei [1 ]
Xu, Hongli [1 ]
Zhang, Guangzhao [1 ,3 ]
Li, Shuai [2 ]
Wang, Chaoyang [3 ]
Lu, Zhouguang [1 ]
Deng, Yonghong [1 ]
机构
[1] Southern Univ Sci & Technol SUSTech, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China
[2] Southern Univ Sci & Technol SUSTech, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China
[3] South China Univ Technol, Res Inst Mat Sci, Guangzhou 510640, Guangdong, Peoples R China
来源
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2018年 / 6卷 / 10期
基金
中国国家自然科学基金;
关键词
Binder; Lignin; Micro silicon; Renewable; Water-soluble; ELECTRICAL ENERGY-STORAGE; HIGH-PERFORMANCE ANODE; HIGH-CAPACITY; NEGATIVE ELECTRODES; ELECTROCHEMICAL PERFORMANCE; RECHARGEABLE BATTERIES; NANOPARTICLE ANODES; POLYMERIC BINDERS; SI ANODES; COMPOSITE;
D O I
10.1021/acssuschemeng.8b01161
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Micro silicon is considered as the most prospective anode material for large-scale application of lithium-ion batteries (LIBs) due to its low production cost and diverse accessibilities. However, micro silicon anodes coupled with conventional binders generally show poor performances in LIBs. Therefore, developing new binders with high performance for micro silicon anode in LIBs is highly desirable. In this work, we report the first lignin-derived water-soluble binder (lignin-graft-sodium polyacrylate, PAL-NaPAA) for the micro silicon anodes. The PAL-NaPAA binder is obtained via a free radical graft copolymerization, followed by an alkaline hydrolysis. The electrochemical performance of PAL-NaPAA is compared with commercial binder carboxymethyl cellulose (CMC) for micro silicon anodes. The electrode using the PAL-NaPAA binder retains a capacity of 1914 mAh g(-1) after 100 cycles at a constant current density of 840 mA g(-1), which is superior to that of the electrode using the CMC binder (1544 mAh g(-1)). Additionally, the successful adhibition of PAL-NaPAA binder to commercial silicon-carbon anodes demonstrates great potential in practical applications in LIBs. It is also found that the lignin-derived binder can significantly accommodate the inevitable volume changes of silicon anode, while maintaining its excellent electrochemical performance. Our results provide a facile approach to utilize the abundant lignin biomass as a novel bind material and have paved the way to the industrial applications of micro silicon-based anodes in LIBs.
引用
收藏
页码:12621 / 12629
页数:17
相关论文
共 50 条
  • [31] A Web-like Three-dimensional Binder for Silicon Anode in Lithium-ion Batteries
    Li, Liyuan
    Li, Tao
    Sha, Yifan
    Ren, Baozeng
    Zhang, Lan
    Zhang, Suojiang
    ENERGY & ENVIRONMENTAL MATERIALS, 2024, 7 (01)
  • [32] An environmental friendly cross-linked polysaccharide binder for silicon anode in lithium-ion batteries
    You, Run
    Han, Xiang
    Zhang, Ziqi
    Li, Lianchuan
    Li, Cheng
    Huang, Wei
    Wan, Jianyuan
    Xu, Jianfang
    Chen, Songyan
    IONICS, 2019, 25 (09) : 4109 - 4118
  • [33] Volumetric Stress Managements on Silicon Anode of Lithium-Ion Batteries by a Self-Adaptable Binder
    Wu, Shuai
    He, Lanying
    Lu, Yue
    Zheng, Jingang
    Li, Lixiang
    Geng, Xin
    Sun, Chengguo
    Zhao, Hongwei
    Jiang, Guangshen
    Di, Fang
    An, Baigang
    ENERGY & ENVIRONMENTAL MATERIALS, 2024,
  • [34] An environmental friendly cross-linked polysaccharide binder for silicon anode in lithium-ion batteries
    Run You
    Xiang Han
    Ziqi Zhang
    Lianchuan Li
    Cheng Li
    Wei Huang
    Jianyuan Wang
    Jianfang Xu
    Songyan Chen
    Ionics, 2019, 25 : 4109 - 4118
  • [35] Maleic anhydride esterified potato starch as the binder in silicon nanoparticles anode for lithium-ion batteries
    Petrus, Himawan Tri Bayu Murti
    Daulay, Amru
    Astuti, Widi
    Supriyatna, Yayat Iman
    Kurniawan, Ade
    Yuwono, Akhmad Herman
    Maulana, Fakhri Akbar
    INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2024, 281
  • [36] Structure-Performance Relationship of Aromatic Polymer Binder for Silicon Anode in Lithium-Ion Batteries
    Kim, Junho
    Kim, Gyuri
    Park, You Kyung
    Lim, Gayoung
    Kim, Seung Tae
    Jung, In Hwan
    Kim, Hansu
    ADVANCED FUNCTIONAL MATERIALS, 2023, 33 (44)
  • [37] A Web-like Three-dimensional Binder for Silicon Anode in Lithium-ion Batteries
    Liyuan Li
    Tao Li
    Yifan Sha
    Baozeng Ren
    Lan Zhang
    Suojiang Zhang
    Energy&EnvironmentalMaterials, 2024, 7 (01) : 25 - 31
  • [38] Investigation on Psyllium Gum as a Bio-Based Binder for Silicon Anode in Lithium-Ion Batteries
    Cingisiz, Sebnem
    Arca, Emin
    Demir-Cakan, Rezan
    CHEMELECTROCHEM, 2024, 11 (20):
  • [39] Epoxy and amide crosslinked polarity enhanced polysaccharides binder for silicon anode in lithium-ion batteries
    Wang, Hongxun
    Wei, Di
    Wan, Zhengwei
    Du, Qiaokun
    Zhang, Bao
    Ling, Min
    Liang, Chengdu
    ELECTROCHIMICA ACTA, 2021, 368
  • [40] Laser cutting of silicon anode for lithium-ion batteries
    Berhe, Mulugeta Gebrekiros
    Oh, Hong Geun
    Park, Seung-Keun
    Lee, Dongkyoung
    JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 2022, 16 : 322 - 334