Connectivity and spacing effects in hydrogen-bonding polymer solutions and blends

被引:0
作者
Painter, P [1 ]
Park, Y [1 ]
Coleman, M [1 ]
机构
[1] Penn State Univ, Polymer Sci Program, University Pk, PA 16802 USA
关键词
hydrogen bonding; polymer blends; polymer solutions;
D O I
10.1002/(SICI)1097-4628(19981114)70:7<1273::AID-APP4>3.0.CO;2-J
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In recent experimental work, it was found that the number of hydrogen bonds in polymer mixtures is strongly influenced by chain-connectivity effects and the spacing of functional groups along the chain. In this article, the relationships between the equilibrium constants used to describe the number of hydrogen bonds in mixtures of various types (blends, solutions, random copolymers, etc.) is elucidated and described. (C) 1998 John Wiley & Sons, Inc. J Appl Polym Sci 70: 1273-1281, 1998.
引用
收藏
页码:1273 / 1281
页数:9
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