Electrochemical and Raman spectroscopic study of polyaniline; influence of the potential on the degradation of polyaniline

被引：147

作者：

Arsov, LD ^{[1
]}

Plieth, W

Kossmehl, G

机构：

[1] Univ St Cyril & Methudius, Fac Technol & Met, Skopje 91000, Macedonia

[2] Tech Univ Dresden, Inst Phys Chem & Electrochem, D-01062 Dresden, Germany

[3] Free Univ Berlin, Inst Organ Chem, D-14195 Berlin, Germany

来源：

JOURNAL OF SOLID STATE ELECTROCHEMISTRY | 1998年 / 2卷 / 05期

关键词：

polyaniline; electropolymerization; cyclic voltammetry; polyaniline degradation; Raman spectroscopy;

D O I：

10.1007/s100080050112

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The polymerization of aniline has been studied employing in-situ electrochemical and Raman spectroscopical techniques. Aniline was polymerized by cyclic voltammetry on a Pt surface in sulfuric acid solutions of aniline. The Raman bands were assigned for degradation products of the overoxidized form of polyaniline. A discussion of the degradation mechanism is given.

引用

页码：355 / 361

页数：7

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