Preparation, Characterization, and Catalytic Behavior of Nanostructured Mesoporous CuO/ZrO2 Catalysts for Low-Temperature CO Oxidation

被引:4
作者
Huang, Jing [1 ]
Wang, Shu-Rong [1 ]
Wu, Shi-Hua [1 ]
机构
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
关键词
CO oxidation; CuO; ZrO2; catalyst; mesoporous; GAS SHIFT REACTION; AU/ZRO2; CATALYSTS; OXIDE; STABILITY; ZIRCONIA; AEROGELS; SUPPORT; TITANIA; ZRO2; H-2;
D O I
10.1080/01932690903269636
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High-surface area mesoporous 20mol% CuO/ZrO2 catalyst was prepared by a surfactant-assisted method of nanocrystalline particle assembly, and characterized by x-ray powder diffraction (XRD), N2 adsorption, transmission electron microscopy (TEM), H2-TPR, TG-DTA, and x-ray photoelectron spectra (XPS) techniques. The catalytic properties of the CuO/ZrO2 nanocatalysts calcined at different temperature were evaluated by low-temperature carbon monoxide oxidation using a CATLAB system. The results showed that these mesoporous nanostructured CuO/ZrO2 catalysts were very active for low-temperature CO oxidation and the CuO/ZrO2 catalyst calcined at 400 degrees C exhibited the highest catalytic activity.
引用
收藏
页码:1469 / 1473
页数:5
相关论文
共 25 条
[11]   Selective oxidation of CO over CuO-CeO2 catalyst:: effect of calcination temperature [J].
Jung, CR ;
Han, J ;
Nam, SW ;
Lim, TH ;
Hong, SA ;
Lee, HI .
CATALYSIS TODAY, 2004, 93-5 :183-190
[12]   Structural and photovoltaic properties of binary TiO2-ZrO2 oxides system prepared by sol-gel method [J].
Kitiyanan, Athapol ;
Sakulkhaemaruethai, Singto ;
Suzuki, Yoshikazu ;
Yoshikawa, Susumu .
COMPOSITES SCIENCE AND TECHNOLOGY, 2006, 66 (10) :1259-1265
[13]   Preferential oxidation of CO in H2 over highly loaded Au/ZrO2 catalysts obtained by direct oxidation of bulk alloy [J].
Lomello-Tafin, M ;
Chaou, AA ;
Morfin, F ;
Caps, V ;
Rousset, JL .
CHEMICAL COMMUNICATIONS, 2005, (03) :388-390
[14]   TPR and TPD studies of CuO/CeO2 catalysts for low temperature CO oxidation [J].
Luo, MF ;
Zhong, YJ ;
Yuan, XX ;
Zheng, XM .
APPLIED CATALYSIS A-GENERAL, 1997, 162 (1-2) :121-131
[15]   Copper-based catalysts for water gas shift reaction: Influence of support on their catalytic activity [J].
Pradhan, S. ;
Reddy, A. Satyanarayana ;
Devi, R. N. ;
Chilukuri, Satyanarayana .
CATALYSIS TODAY, 2009, 141 (1-2) :72-76
[16]   Surfactant-assisted preparation of hollow microspheres of mesoporous TiO2 [J].
Ren, TZ ;
Yuan, ZY ;
Su, BL .
CHEMICAL PHYSICS LETTERS, 2003, 374 (1-2) :170-175
[17]   Mesoporous CeO2:: Synthesis by nanocasting, characterisation and catalytic properties [J].
Roggenbuck, Jan ;
Schaefer, Hanno ;
Tsoncheva, Tanya ;
Minchev, Christo ;
Hanss, Jan ;
Tiemann, Michael .
MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 101 (03) :335-341
[18]   XPES STUDIES OF OXIDES OF 2ND-ROW AND 3RD-ROW TRANSITION-METALS INCLUDING RARE-EARTHS [J].
SARMA, DD ;
RAO, CNR .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1980, 20 (1-2) :25-45
[19]   HIGH-SURFACE-AREA TITANIA AEROGELS - PREPARATION AND STRUCTURAL-PROPERTIES [J].
SCHNEIDER, M ;
BAIKER, A .
JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (06) :587-589
[20]   Origin of oxide sensitivity in gold-based catalysts:: A first principle study of CO oxidation over au supported on monoclinic and tetragonal ZrO2 [J].
Wang, Chuan-Ming ;
Fan, Kang-Nian ;
Liu, Zhi-Pan .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (09) :2642-2647