共 25 条
Preparation, Characterization, and Catalytic Behavior of Nanostructured Mesoporous CuO/ZrO2 Catalysts for Low-Temperature CO Oxidation
被引:4
作者:
Huang, Jing
[1
]
Wang, Shu-Rong
[1
]
Wu, Shi-Hua
[1
]
机构:
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
关键词:
CO oxidation;
CuO;
ZrO2;
catalyst;
mesoporous;
GAS SHIFT REACTION;
AU/ZRO2;
CATALYSTS;
OXIDE;
STABILITY;
ZIRCONIA;
AEROGELS;
SUPPORT;
TITANIA;
ZRO2;
H-2;
D O I:
10.1080/01932690903269636
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
High-surface area mesoporous 20mol% CuO/ZrO2 catalyst was prepared by a surfactant-assisted method of nanocrystalline particle assembly, and characterized by x-ray powder diffraction (XRD), N2 adsorption, transmission electron microscopy (TEM), H2-TPR, TG-DTA, and x-ray photoelectron spectra (XPS) techniques. The catalytic properties of the CuO/ZrO2 nanocatalysts calcined at different temperature were evaluated by low-temperature carbon monoxide oxidation using a CATLAB system. The results showed that these mesoporous nanostructured CuO/ZrO2 catalysts were very active for low-temperature CO oxidation and the CuO/ZrO2 catalyst calcined at 400 degrees C exhibited the highest catalytic activity.
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页码:1469 / 1473
页数:5
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