Structure and magnetic properties of diaqua(4,4′-bipyridine) terbium(III) and the zinc(II) carboxylate dimer [Tb2Zn2(CH2C(CH3)COO)10(bipy)(H2O)2]2

被引：10

作者：

Wu, B ^{[1
]}

Lu, WM ^{[1
]}

Wu, FF ^{[1
]}

Zheng, XM ^{[1
]}

机构：

[1] Zhejiang Univ, Inst Catalysis, Hangzhou 310028, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2003年 / 28卷 / 06期

关键词：

D O I：

10.1023/A:1025428005520

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel heteronuclear complex, [Tb2Zn2L10(bipy)(H2O)(2)](2) (HL = alpha-methylacrylic acid, bipy = 4,4'-bipyridine), was synthesized and characterized by elemental analysis and i.r. absorption spectra. Its structure, determined by X-ray diffraction, is a discrete octanuclear molecule, in which two Zn-II ions are linked by a bipy molecule and between Tb-III ions, or Tb-III and Zn-II ions are bridged by bidentate alpha-methylacrylato groups. The temperature dependence of the magnetic susceptibility of the complex shows strong ferromagnetic interaction between the terbium atoms.

引用

页码：694 / 697

页数：4

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