Synthesis, characterization and polymerization potential of ansa-metallocene dichloride complexes of titanium, zirconium and hafnium containing a Si-N-Si bridging unit

被引：21

作者：

Alt, HG ^{[1
]}

Fottinger, K ^{[1
]}

Milius, W ^{[1
]}

机构：

[1] Univ Bayreuth, Anorgan Chem Lab, D-95440 Bayreuth, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 564卷 / 1-2期

关键词：

group IV metal; amino silyl cyclopentadienyl; indenyl; ansa-metallocene dichloride; ethylene polymerization;

D O I：

10.1016/S0022-328X(98)00640-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five new Si-N-Si bridged metallocene dichloride complexes of the type [CpSiMe2N(R)SiMe2-Cp]MCl2 (Cp = C5H4, C9H6; R = alkyl, M = Ti, Zr, Hf) were synthesized using a new type of amine elimination reaction. All complexes were characterized by H-1-, C-13-, N-15- and Si-29-NMR spectroscopy. An X-ray structure analysis was performed for complex [C5H4-SiMe2N(Bu-n)SiMe2-C5H4]HfCl2 (4) (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：109 / 114

页数：6

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