Analysis of Fe2O3 and Fe3O4 dissolution kinetics in terms of the chain mechanism model

被引：8

作者：

Chastukhin, AE

Izotov, AD

Gorichev, IG

Kutepov, AM

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

[2] Moscow State Pedag Univ, Moscow 129242, Russia

[3] Moscow State Univ Environm Engn, Moscow 107884, Russia

来源：

THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING | 2003年 / 37卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1023/A:1025084705089

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Kinetic data on Fe2O3 and Fe3O4 dissolution in solutions of hydrochloric and sulfuric acids of different concentrations are analyzed in terms of the chain mechanism model at different solution temperatures under different conditions of synthesis of oxide samples. A kinetic model of dissolution of iron oxides is proposed. It is shown that features of the iron oxide dissolution kinetics are explained by the difference between the concentrations of dislocations and other defects on the surface of particles.

引用

页码：398 / 406

页数：9

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