Anodic behavior of zinc in Zn-MnO2 battery using ERDA technique

被引：49
作者：
Minakshi, Manickam [1 ]
Ionescu, Mihail [2 ]
机构：
[1] Murdoch Univ, Fac Minerals & Energy, Murdoch, WA 6150, Australia
[2] ANSTO, Inst Environm Engn, Menai, NSW 2234, Australia
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2010年 / 35卷 / 14期
基金：
澳大利亚研究理事会;
关键词：
Zinc; Manganese dioxide; Rechargeable; Battery; LiOH; Electrolyte; MNO2; CATHODE; RECHARGEABILITY; PERFORMANCE; CELLS;
D O I：
10.1016/j.ijhydene.2010.04.143
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The commercial, alkaline zinc-manganese dioxide (Zn-MnO2) primary battery has been transformed into a secondary battery using lithium hydroxide electrolyte. Galvanostatic discharge charge experiments showed that the capacity decline of the Zn-MnO2 battery is not caused by the MnO2 cathode, but by the zinc anode. The electrochemical data indicated that a rechargeable battery made of porous zinc anode can have a larger discharge capacity of 220 mAh/g than a planar zinc anode of 130 mAh/g. The cycling performance of these two anodes is demonstrated. Structural and depth profile analyses of the discharged anodes are examined by X-ray diffraction (XRD) and elastic recoil detection analysis (ERDA) techniques. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：7618 / 7622
页数：5
相关论文
共 50 条
[31]   Electrochemical recycling of Zn from spent Zn-MnO2 batteries [J].
Garcia, Eric M. ;
Taroco, Hosane A. ;
Melo, Julio O. F. ;
Silva, Ana Paula C. M. ;
Oliveira, Ione M. F. .
IONICS, 2013, 19 (11) :1699-1703
[32]   Achieving mesoporous MnO2@polyaniline nanohybrids via a gas/liquid interfacial reaction between aniline and KMnO4 aqueous solution towards Zn-MnO2 battery [J].
Huang, Juan ;
Tu, Jinying ;
Lv, Yan ;
Liu, Yulan ;
Huang, Huabo ;
Li, Liang ;
Yao, Junlong .
SYNTHETIC METALS, 2020, 266
[33]   Role of zinc hydroxysulfates in the thermodynamics and kinetics of mild-acid Zn-MnO2 batteries [J].
Ha, Kwang-Ho ;
Moon, Hyeonseok ;
Joo, Eun Ji ;
Jo, Duk Hyung ;
Lee, Kyu Tae .
ENERGY STORAGE MATERIALS, 2024, 65
[34]   An in-depth mechanistic insight into the redox reaction and degradation of aqueous Zn-MnO2 batteries [J].
You, Zongyuan ;
Hua, Wei ;
Li, Na ;
Liu, Huanyan ;
Wang, Jian-Gan .
CHINESE CHEMICAL LETTERS, 2023, 34 (04)
[35]   Parasitic electrodeposition in Zn-MnO2 batteries and its suppression for prolonged cyclability [J].
Liang, Ruilin ;
Fu, Jing ;
Deng, Ya-Ping ;
Pei, Yi ;
Zhang, Maiwen ;
Yu, Aiping ;
Chen, Zhongwei .
ENERGY STORAGE MATERIALS, 2021, 36 (36) :478-484
[36]   Hydroponics Polymer Gels for Zn-MnO2 Alkaline Batteries [J].
Ismail, Yanny Marliana Baba ;
Haliman, Habsah ;
Mohamad, Ahmad Azmin .
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2012, 7 (04) :3555-3566
[37]   Achieving Ultrahigh Energy Density and Long Durability in a Flexible Rechargeable Quasi-Solid-State Zn-MnO2 Battery [J].
Zeng, Yinxiang ;
Zhang, Xiyue ;
Meng, Yue ;
Yu, Minghao ;
Yi, Jianan ;
Wu, Yiqiang ;
Lu, Xihong ;
Tong, Yexiang .
ADVANCED MATERIALS, 2017, 29 (26)
[38]   Towards storable and durable Zn-MnO2 batteries with hydrous tetraglyme electrolyte [J].
Ma, Kaixuan ;
Yang, Gongzheng ;
Wang, Chengxin .
JOURNAL OF ENERGY CHEMISTRY, 2023, 80 :432-441
[39]   Decoupling the Dynamics of Zinc Hydroxide Sulfate Precipitation/Dissolution in Aqueous Zn-MnO2 Batteries by Operando Optical Microscopy: A Missing Piece of the Mechanistic Puzzle [J].
Godeffroy, Louis ;
Aguilar, Ivette ;
Medard, Jerome ;
Larcher, Dominique ;
Tarascon, Jean-Marie ;
Kanoufi, Frederic .
ADVANCED ENERGY MATERIALS, 2022, 12 (30)
[40]   Zn/MnO2 Battery Chemistry With H+ and Zn2+ Coinsertion [J].
Sun, Wei ;
Wang, Fei ;
Hou, Singyuk ;
Yang, Chongyin ;
Fan, Xiulin ;
Ma, Zhaohui ;
Gao, Tao ;
Han, Fudong ;
Hu, Renzong ;
Zhu, Min ;
Wang, Chunsheng .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (29) :9775-9778
12345