Valorization of levulinic acid over non-noble metal catalysts: challenges and opportunities

被引：141

作者：

Xue, Zhimin ^{[1
]}

Liu, Qiaoling ^{[1
]}

Wang, Jinfang ^{[2
]}

Mu, Tiancheng ^{[2
]}

机构：

[1] Beijing Forestry Univ, Coll Mat Sci & Technol, Beijing Key Lab Lignocellulos Chem, Beijing 100083, Peoples R China

[2] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China

来源：

GREEN CHEMISTRY | 2018年 / 20卷 / 19期

基金：

中国国家自然科学基金;

关键词：

VAPOR-PHASE HYDROGENATION; HIGHLY EFFICIENT HYDROGENATION; MESOPOROUS H3PW12O40-SILICA COMPOSITE; SUPPORTED PALLADIUM NANOPARTICLES; GAMMA-VALEROLACTONE; ETHYL-LEVULINATE; DIPHENOLIC ACID; SELECTIVE HYDROGENATION; FORMIC-ACID; REDUCTIVE AMINATION/CYCLIZATION;

D O I：

10.1039/c8gc02001a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Levulinic acid (LA), easily derived from cellulose via an acid catalytic process, is an attractive biomass-derived platform chemical which can be converted into various valuable chemicals, and LA valorization is an important component in biomass transformation. For LA conversion, non-noble metal catalytic systems have attracted significant attention due to their low cost compared with noble metals, and much progress has been achieved in recent years. This review focuses on the efficient and selective transformation of LA into a diverse range of products in non-noble metal catalytic systems. A reasonable outlook is presented in the last part of the review to highlight the challenges and opportunities associated with LA upgrading over non-noble metal catalysts.

引用

页码：4391 / 4408

页数：18

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