Catalytic behavior of niobium-containing SBA-15 molecular sieves in the oxidation of cyclohexene

被引：0
作者：
Nowak, I [1 ]
机构：
[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland
来源：
RECENT ADVANCES IN THE SCIENCE AND TECHNOLOGY OF ZEOLITES AND RELATED MATERIALS, PTS A - C | 2004年 / 154卷
关键词：
NbSBA-15; niobium source; cyclohexene; oxidation;
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Activity and selectivity of niobium-containing mesoporous molecular sieves have been tested in liquid phase oxidation of cyclohexene. On the basis of this investigation the new efficient NbSBA- 15 catalyst prepared from niobium chloride via conventional synthesis, has been selected. Moreover, other NbSBA-15 show high activity in this reaction (the yield of epoxide is higher than 40%). It has been shown that all NbSBA-15 catalysts are efficient in the reaction of cyclohexene oxidation and their activity can be explained with difference in pore diameters.
引用
收藏
页码：2936 / 2944
页数：9
相关论文
共 50 条
  • [41] Enhanced catalytic activity over vanadium-containing silylated SBA-15 catalysts for styrene epoxidation and benzene hydroxylation
    Hu, Liya
    Yue, Bin
    Wang, Cheng
    Chen, Xueying
    He, Heyong
    APPLIED CATALYSIS A-GENERAL, 2014, 477 : 141 - 146
  • [42] Catalytic activity of Fe/SBA-15 for ozonation of dimethyl phthalate in aqueous solution
    Huang, Ruihuan
    Yan, Huihua
    Li, Laisheng
    Deng, Dayi
    Shu, Yuehong
    Zhang, Qiuyun
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 106 (1-2) : 264 - 271
  • [43] Catalytic application of an organo superbase denderon grafted on mesoporous SBA-15 and related palladium complex in the aerobic oxidation of alcohols
    Veisi, Hojat
    Kordestani, Davood
    Sajjadifar, Sami
    Hamelian, Mona
    IRANIAN CHEMICAL COMMUNICATION, 2014, 2 (01) : 27 - 33
  • [44] Ru/SBA-15 catalysts for partial hydrogenation of benzene to cyclohexene: Tuning the Ru crystallite size by Ba
    Bu, Juan
    Liu, Jian-Liang
    Chen, Xue-Ying
    Zhuang, Ji-Hua
    Yan, Shi-Run
    Qiao, Ming-Hua
    He, He-Yong
    Fan, Kang-Nian
    CATALYSIS COMMUNICATIONS, 2008, 9 (15) : 2612 - 2615
  • [45] Catalytic aerobic oxidation of acetaldehyde over Keggin-type molybdovanadophosphoric acid/SBA-15 under ambient condition
    Zhou Yan
    Yue Bin
    Bao Ren-Lie
    Liu Shi-Xi
    He He-Yong
    CHINESE JOURNAL OF CHEMISTRY, 2006, 24 (08) : 1001 - 1005
  • [46] POLYMER BOUND TRANSITION METAL COMPLEXES FOR CATALYTIC OXIDATION OF CYCLOHEXENE WITH MOLECULAR OXYGEN
    HAO Chengjun ZhAO Ganqing College of Chemistry and Chemical Engineering
    Chinese Journal of Reactive Polymers, 2007, (Z1) : 66 - 71
  • [47] Prominent catalytic activity of mesoporous molecular sieves in the vapor phase dehydration of cyclohexanol to cyclohexene
    Azhagapillai Prabhu
    Ahmed Al Shoaibi
    Chandrasekar Srinivasakannan
    Muthaiahpillai Palanichamy
    Velayutham Murugesan
    Journal of Rare Earths, 2013, 31 (05) : 477 - 484
  • [48] The effect of Ag and CeO2 distribution on SBA-15 surface on the activity of Ag–CeO2/SBA-15 catalysts in CO and methanol oxidation
    N. N. Mikheeva
    V. I. Zaikovskii
    G. V. Mamontov
    Journal of Sol-Gel Science and Technology, 2019, 92 : 398 - 407
  • [49] Mesoporous Ti-KIT-6 molecular sieves: Their catalytic activity in the epoxidation of cyclohexene
    Kumaresan, L.
    Prabhu, A.
    Palanichamy, M.
    Murugesan, V.
    JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2010, 41 (06) : 670 - 675
  • [50] The effect of Ag and CeO2 distribution on SBA-15 surface on the activity of Ag-CeO2/SBA-15 catalysts in CO and methanol oxidation
    Mikheeva, N. N.
    Zaikovskii, V. I.
    Mamontov, G. V.
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2019, 92 (02) : 398 - 407
12345