Butyltin compounds in sediments of the Bahia Blanca Estuary, Argentina

被引:23
作者
Delucchi, Federico
Tombesi, Norma B.
Freije, Ruben H.
Marcovecchio, Jorge E.
机构
[1] Consejo Nacl Invest Cient & Tecn, IADO, Lab Quim Marina, Bahia Blanca, Buenos Aires, Argentina
[2] Univ Nacl Sur, Lab Quim Ambiental, RA-8000 Bahia Blanca, Argentina
[3] UTN, FRBB, Bahia Blanca, Argentina
[4] Univ Fraternidad Agrupaciones Santo Tomas Aquino, Mar Del Plata, Argentina
关键词
antifouling paints; Argentina; Bahia Blanca Estuary; Dibutyltin; dry dock; organotin compounds; sediments; Tributyltin;
D O I
10.1007/s10661-006-9547-4
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Systematic measurements of both Tributyltin (TBT) and Dibutyltin (DBT) in sediments along different locations in the inner zone of Bahia Blanca estuary were done. Two samples were taken near the main dry dock facility, at Puerto Belgrano naval base, in Argentina. TBT concentrations from non-detected to 170.3 ng Sn g(-1) were measured in the inner region of the estuary, and higher one of 3,288 ng Sn g(-1) near the dry dock at Puerto Belgrano. DBT values ranging between non-detected and 75.2 ng Sn g(-1) were obtained along the principal channel, but extreme concentration of 1,645 ng Sn g(-1) was measured at Puerto Belgrano. These values show that this estuary is affected by organotin pollution, mainly in areas of heavy shipyard activities.
引用
收藏
页码:445 / 451
页数:7
相关论文
共 20 条
[1]   Speciation of organotin compounds in sediment cores from Guanabara Bay, Rio de Janeiro (Brazil) by gas chromatography-pulsed flame photometric detection [J].
Almeida, AC ;
Wagener, ADR ;
Maia, CB ;
Miekeley, N .
APPLIED ORGANOMETALLIC CHEMISTRY, 2004, 18 (12) :694-704
[2]   Tributyltin: case study of a chronic contaminant in the coastal environment [J].
Alzieu, C .
OCEAN & COASTAL MANAGEMENT, 1998, 40 (01) :23-36
[3]   Impact of tributyltin on marine invertebrates [J].
Alzieu, C .
ECOTOXICOLOGY, 2000, 9 (1-2) :71-76
[4]  
*AOAC, 1993, PEERV METH PROGR
[5]   Butyltins in water, biofilm, animals and sediments of the west coast of India [J].
Bhosle, NB ;
Garg, A ;
Jadhav, S ;
Harjee, R ;
Sawant, SS ;
Venkat, K ;
Anil, AC .
CHEMOSPHERE, 2004, 57 (08) :897-907
[6]  
BOTTE S, 2005, THESIS U NAC SUR BAH
[7]   Organotin compounds in sediments from the Gota alv estuary [J].
Brack, K .
WATER AIR AND SOIL POLLUTION, 2002, 135 (1-4) :131-140
[8]   Speciation of butyltin compounds in marine sediments with headspace solid phase microextraction and gas chromatography-mass spectrometry [J].
Cardellicchio, N ;
Giandomenico, S ;
Decataldo, A ;
Di Leo, A .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 2001, 369 (06) :510-515
[9]   Organotin contamination in sediments from the Western Mediterranean enclosures following 10 years of TBT regulation [J].
Díez, S ;
Abalos, M ;
Bayona, JM .
WATER RESEARCH, 2002, 36 (04) :905-918
[10]   Gas chromatography-high-resolution mass spectrometry based method for the simultaneous determination of nine organotin compounds in water, sediment and tissue [J].
Ikonomou, MG ;
Fernandez, MP ;
He, T ;
Cullon, D .
JOURNAL OF CHROMATOGRAPHY A, 2002, 975 (02) :319-333