Heat Capacity of an Ethylene Glycol-Dimethylsulfoxide System

被引:0
作者
Tyurin, A., V [1 ]
Solonina, I. A. [1 ]
Rodnikova, M. N. [1 ]
Sirotkin, D. A. [1 ]
机构
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
INACCESSIBLE CRITICAL-POINT; AQUEOUS-SOLUTIONS; LIGHT-SCATTERING; BULK PROPERTIES; MIXTURES;
D O I
10.1134/S0036024421080288
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The heat capacity of an ethylene glycol (EG)-dimethylsulfoxide (DMSO) liquid system is measured to determine its solvophobic effect. Measurements are made in the temperature range of 300-340 K for pure DMSO and the 0 to similar to 15 and 50 mol % ranges of DMSO concentrations. The concentration dependences of the apparent and excess apparent heat capacities of DMSO are calculated at five given temperatures. The results are explained from the viewpoint of the weak solvophobic effect in the studied EG-DMSO system.
引用
收藏
页码:1551 / 1554
页数:4
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