Structure and magnetic behaviour of a novel alternating one-dimensional chain compound {[Cu(phen)(μ1,1-N3)]2(μ-ta)}n

被引：41
|
作者：
Li, LC [1 ]
Liao, DZ
Jiang, ZH
Yan, SP
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
来源：
POLYHEDRON | 2001年 / 20卷 / 7-8期
关键词：
azide; copper(II) compound; crystal structure; magnetic properties; terephthalate;
D O I：
10.1016/S0277-5387(01)00705-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new one-dimensional alternating chain compound {[Cu(phen)(mu (1,1)-N-3)](2)(mu -ta)} (phen = 1, 10-phenanthroline, ta = terephthalato dianion) has been prepared and characterised by X-ray crystallography and magnetic measurements. The structure consists of copper chains in which the copper(II) ions are alternatively bridged by terephalato and double end-on azido bridges. In the temperature range 4-300 K, the variable temperature magnetic susceptibility of the title compound can be modelled as a dimeric copper species within which the exchange interaction is ferromagnetic. (C) 2001 Elsevier Science B.V. All rights reserved.
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收藏
页码：681 / 684
页数：4
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