The liquid junction potential in potentiometric titrations.: VII.: On emf titrations proposed for the determination of some interaction coefficients

被引:3
作者
Néher-Neumann, E [1 ]
机构
[1] Royal Inst Technol KTH, Dept Chem Inorgan Chem, S-10044 Stockholm, Sweden
关键词
liquid junction potential; ionic activity factors; specific interaction theory; interaction coefficients;
D O I
10.1023/A:1026348523861
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Certain galvanic cells without liquid junctions, used together with a titration technique, are proposed to determine interaction coefficients for the various ion pairs present in the solutions: The experimental values of the interaction coefficients are needed in calculations of the total emf of cells with liquid junctions considered in other papers of this series.
引用
收藏
页码:645 / 662
页数:18
相关论文
共 26 条
[1]  
Biedermann G., 1982, Scientific Basis for Nuclear Waste Management V. Proceedings of the Materials Research Society Fifth International Symposium on the Scientific Basis for Nuclear Waste, P791
[2]  
BIEDERMANN G, 1971, CHEM SCRIPTA, V1, P155
[3]  
BIEDERMANN G, 1974, CHEM SCRIPTA, V5, P153
[4]  
BIEDERMANN G, 1980, CHEM SCRIPTA, V16, P138
[5]  
BIEDERMANN G, 1964, ARK KEMI, V22, P253
[6]  
Biedermann G., COMMUNICATION
[7]  
BIEDERMANN G, 1975, NATURE SEAWATER, P339
[8]   Studies on solubility IV The principle of the specific interaction of ions [J].
Bronsted, JN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1922, 44 :877-898
[9]   Calculation of the osmotic and activity functions in solutions of uni-univalent salts [J].
Bronsted, JN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1922, 44 :938-948
[10]   A type of silver chloride electrode suitable for use in dilute solutions [J].
Brown, AS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1934, 56 :646-647