Single crystal growth and characterization of GdRh2Si2

被引:19
作者
Kliemt, K. [1 ]
Krellner, C. [1 ]
机构
[1] Goethe Univ Frankfurt, Inst Phys, Kristall & Mat Lab, D-60438 Frankfurt, Germany
关键词
Bridgman technique; Growth from high-temperature solutions; Single crystal growth; Gadolinium compounds; Magnetic materials; Rare earth compounds; RARE-EARTH; TBRH2SI2; SUPERCONDUCTIVITY; SPECTROSCOPY; TEMPERATURE; TRANSITION; ITINERANT; MAGNETISM; YBRH2SI2; GDT2SI2;
D O I
10.1016/j.jcrysgro.2015.02.079
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
High-temperature indium flux growth was applied to prepare single crystals of GdRh2Si2 by a modified Bridgman method leading to mm-sized single crystals with a platelet habitus. Specific heat and susceptibility data of GdRh2Si2 exhibit a pronounced anomaly at T-N = 107 K, where the antiferromagnetic ordering sets in Magnetic measurements on the single crystals were performed down to T=2 K in external fields from B=0 to 9T applied along the [100]-, [110]- and [001]-direction of the tetragonal lattice. The effective magnetic moment determined from a Curie-Weiss fit agrees well with experimental values from literature, but is larger than the theoretically predicted value. Electrical transport data recorded for current flow parallel and perpendicular to the [001]-direction show a large anisotropy below T-N. The residual resistivity ratio RRR = rho(300) (K)/rho(0) similar to 23 demonstrates that we succeeded in preparing high-quality crystals using high-temperature indium flux-growth. (C) 2015 Elsevier B.V. All rights reserved,
引用
收藏
页码:37 / 41
页数:5
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