Highly fluorescent dendrimers containing stilbene, and 4-styrylstilbene with resorcinarene cores:: Synthesis and optical properties

被引:8
作者
Lijanova, Irina Victorovna
Moggio, Ivana
Arias, Eduardo
Vazquez-Garcia, Rosa
Martnez-Garcia, Marcos
机构
[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico
[2] Ctr Invest Quim Aplicada, Saltillo 5253, Coahuila, Mexico
关键词
stilbenes; pi-conjugated systems; resorcinarene; dendrimers;
D O I
10.1166/jnn.2007.917
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dendron conjugated branches of stilbene and 4-styrylstilbene groups have been attached to resorcinarene cores. A noticeable effect in solution for all dendrimers was observed in the fluorescence quantum yield. The optical properties do not change with concentration in solution. The optical properties of thin films are identical to those of the solutions indicating the absence of intermolecular interactions. The dendrimers were characterized by I H, C-13 NMR, FTIR, UV-Vis, fluorescence spectroscopy, MALDI-TOF or FAB+ mass spectrometry, and elemental analysis.
引用
收藏
页码:3607 / 3614
页数:8
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