Effective Degradation of Rh 6G Using Montmorillonite-Supported Nano Zero-Valent Iron under Microwave Treatment

被引:17
作者
Rao, Wenxiu [1 ]
Liu, Hao [2 ]
Lv, Guocheng [1 ]
Wang, Danyu [1 ]
Liao, Libing [1 ]
机构
[1] China Univ Geosci, Sch Mat Sci & Technol, Natl Lab Mineral Mat, Beijing Key Lab Mat Utilizat Nonmetall Minerals &, Beijing 100083, Peoples R China
[2] China Univ Geosci, Sch Sci, Beijing 100083, Peoples R China
来源
MATERIALS | 2018年 / 11卷 / 11期
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
nano zero-valent iron; montmorillonite; organic dyes; Fenton-like reaction; microwave; ENHANCED PHOTOCATALYTIC PERFORMANCE; DYEING WASTE-WATER; CARBON NANOTUBES; FENTON CATALYST; METHYLENE-BLUE; REMOVAL; NZVI; REMEDIATION; MECHANISMS; OXIDATION;
D O I
10.3390/ma11112212
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nano zero-valent iron has drawn great attention for the degradation of organic dyes due to its high reactivity, large specific surface area, lightweight, and magnetism. However, the aggregation and passivation of iron nanoparticles may prohibit the wide use of it. A new composite material was prepared by loading nano zero-valent iron (nZVI) on montmorillonite (MMT) to overcome the above shortcomings and it was further used for the removal of Rhodamine 6G (Rh 6G) under microwave treatment in the present work. The effects of various parameters, including the initial concentration of Rh 6G, microwave power, and pH value were investigated. The new composite material (nZVI/MMT) showed an excellent degradation ability for removing Rh 6G, and the removal amount reached 500 mg/g within 15 min. The degradation rate reached 0.4365 min(-1), significantly higher than most previous reports using other removal methods for Rh 6G.
引用
收藏
页数:11
相关论文
共 54 条
  • [1] Carriers for nano zerovalent iron (nZVI): synthesis, application and efficiency
    Adusei-Gyamfi, Junias
    Acha, Victor
    [J]. RSC ADVANCES, 2016, 6 (93): : 91025 - 91044
  • [2] Microwave-induced carbon nanotubes catalytic degradation of organic pollutants in aqueous solution
    Chen, Jing
    Xue, Shuang
    Song, Youtao
    Shen, Manli
    Zhang, Zhaohong
    Yuan, Tianxin
    Tian, Fangyuan
    Dionysiou, Dionysios D.
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2016, 310 : 226 - 234
  • [3] A novel strategy for preparation of an effective and stable heterogeneous photo-Fenton catalyst for the degradation of dye
    Chen, Shanshan
    Wu, Yuhan
    Li, Gang
    Wu, Jianning
    Meng, Guihua
    Guo, Xuhong
    Liu, Zhiyong
    [J]. APPLIED CLAY SCIENCE, 2017, 136 : 103 - 111
  • [4] Novel low-cost Fenton-like layered Fe-titanate catalyst: Preparation, characterization and application for degradation, of organic colorants
    Chen, Yongzhou
    Li, Nian
    Zhang, Ye
    Zhang, Lide
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2014, 422 : 9 - 15
  • [5] Lightweight and Flexible Graphene Foam Composites for High-Performance Electromagnetic Interference Shielding
    Chen, Zongping
    Xu, Chuan
    Ma, Chaoqun
    Ren, Wencai
    Cheng, Hui-Ming
    [J]. ADVANCED MATERIALS, 2013, 25 (09) : 1296 - 1300
  • [6] Two hybrid Au-ZnO aggregates with different hierarchical structures: A comparable study in photocatalysis
    Cheng, Yi-Feng
    Jiao, Wenling
    Li, Qingqing
    Zhang, Yu
    Li, Sesi
    Li, Dandan
    Che, Renchao
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2018, 509 : 58 - 67
  • [7] Nanoscale zero-valent iron/biochar composite as an activator for Fenton-like removal of sulfamethazine
    Deng, Junmin
    Dong, Haoran
    Zhang, Cong
    Jiang, Zhao
    Cheng, Yujun
    Hou, Kunjie
    Zhang, Lihua
    Fan, Changzheng
    [J]. SEPARATION AND PURIFICATION TECHNOLOGY, 2018, 202 : 130 - 137
  • [8] Effects of nano-sized zero-valent iron (nZVI) on DDT degradation in soil and its toxicity to collembola and ostracods
    El-Temsah, Yehia S.
    Joner, Erik J.
    [J]. CHEMOSPHERE, 2013, 92 (01) : 131 - 137
  • [9] Sulfur-mediated synthesis of N-doped carbon supported cobalt catalysts derived from cobalt porphyrin for ethylbenzene oxidation
    Fu, Lingling
    Chen, Yuan
    Zhao, Sufang
    Liu, Zhigang
    Zhu, Runliang
    [J]. RSC ADVANCES, 2016, 6 (23): : 19482 - 19491
  • [10] Adsorption characteristics and the kinetics of the cation exchange of rhodamine-6G with Na+-montmorillonite
    Gemeay, AH
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 251 (02) : 235 - 241