Triggering a transient organo-gelation system in a chemically active solvent

被引:6
作者
Chevigny, Romain [1 ]
Schirmer, Johanna [1 ]
Piras, Carmen C. [2 ]
Johansson, Andreas [1 ,3 ]
Kalenius, Elina [1 ]
Smith, David K. [2 ]
Pettersson, Mika [1 ]
Sitsanidis, Efstratios D. [1 ]
Nissinen, Maija [1 ]
机构
[1] Univ Jyvaskyla, Nanosci Ctr, Dept Chem, POB 35, FI-40014 Jyu, Finland
[2] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
[3] Univ Jyvaskyla, Nanosci Ctr, Dept Phys, POB 35, FT-40014 Jyu, Finland
关键词
HYDROGELS; DRIVEN; DESIGN;
D O I
10.1039/d1cc04021a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A transient organo-gelation system with spatiotemporal dynamic properties is described. Here, the solvent actively controls a complex set of equilibria that underpin the dynamic assembly event. The observed metastability is due to the in situ formation of a secondary solvent, acting as an antagonist against the primary solvent of the organogel.
引用
收藏
页码:10375 / 10378
页数:4
相关论文
共 32 条
  • [1] Sucrose-fueled, energy dissipative, transient formation of molecular hydrogels mediated by yeast activity
    Angulo-Pachon, Cesar A.
    Miravet, Juan F.
    [J]. CHEMICAL COMMUNICATIONS, 2016, 52 (31) : 5398 - 5401
  • [2] Boekhoven J., 2010, Angew. Chemie, V122, P4935, DOI DOI 10.1002/ANIE.201001511
  • [3] Transient assembly of active materials fueled by a chemical reaction
    Boekhoven, Job
    Hendriksen, Wouter E.
    Koper, Ger J. M.
    Eelkema, Rienk
    van Esch, Jan H.
    [J]. SCIENCE, 2015, 349 (6252) : 1075 - 1079
  • [4] Temporal Control over Transient Chemical Systems using Structurally Diverse Chemical Fuels
    Chen, Jack L. -Y.
    Maiti, Subhabrata
    Fortunati, Ilaria
    Ferrante, Camilla
    Prins, Leonard J.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (48) : 11549 - 11559
  • [5] Self-Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media
    Chen, Shaoyu
    Costil, Romain
    Leung, Franco King-Chi
    Feringa, Ben L.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (21) : 11604 - 11627
  • [6] Phenylalanine and derivatives as versatile low-molecular-weight gelators: design, structure and tailored function
    Das, Tanmay
    Haering, Marleen
    Haldar, Debasish
    Diaz Diaz, David
    [J]. BIOMATERIALS SCIENCE, 2017, 6 (01) : 38 - 59
  • [7] Transient self-assembly of molecular nanostructures driven by chemical fuels
    della Sala, Flavio
    Neri, Simona
    Maiti, Subhabrata
    Chen, Jack L-Y
    Prins, Leonard J.
    [J]. CURRENT OPINION IN BIOTECHNOLOGY, 2017, 46 : 27 - 33
  • [8] Temporally Controlled Supramolecular Polymerization
    Dhiman, Shikha
    George, Subi J.
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2018, 91 (04) : 687 - 699
  • [9] Low-Molecular-Weight Gels: The State of the Art
    Draper, Emily R.
    Adams, Dave J.
    [J]. CHEM, 2017, 3 (03): : 390 - 410
  • [10] Supramolecular Hydrogelators and Hydrogels: From Soft Matter to Molecular Biomaterials
    Du, Xuewen
    Zhou, Jie
    Shi, Junfeng
    Xu, Bing
    [J]. CHEMICAL REVIEWS, 2015, 115 (24) : 13165 - 13307