Hydrothermal synthesis, crystal structure and magnetic properties of a new 2D layered vanadium oxide complex:: [Ni(phen)(H2O)]2V4O12

被引：2

作者：

Liu, CM ^{[1
]}

Gao, S

Zhang, DQ

Zhu, DB

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China

[2] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 58卷 / 04期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; nickel(II) complex; vanadium oxide; 1,10-phenanthroline; crystal structure; magnetic properties;

D O I：

10.1080/0095897042000327923

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new organic-inorganic hybrid vanadium oxide complex, [Ni(phen)(H2O)](2)V4O12, 1 (phen = 1,10-phenanthroline), has been synthesized using a hydrothermal method and structurally characterized. Complex I exhibits a layered structure in which vanadium oxide chains, {V2O6}(2n-)(n) are linked to [Ni(phen)(H2O)](2+) subunits to form a two-dimensional (2D) topology. Crystals are triclinic, space group P (1) over bar, with a = 7.869(2), b = 9.437(2), 20.992(4) angstrom, alpha = 89.95(3), beta = 89.84(3), gamma = 67.22(3)degrees, V = 1437.3(5)angstrom(3) and Z = 2. Magnetic measurements indicate that 1 exhibits a weak ferromagnetic exchange interaction.

引用

页码：327 / 334

页数：8

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