A new steroidal glycoside phrygioside A and its aglycone from the starfish Hippasteria phrygiana

被引：9

作者：

Levina, EV ^{[1
]}

Kalinovskii, AI ^{[1
]}

Andriyashchenko, PV ^{[1
]}

Dmitrenok, PS ^{[1
]}

Evtushenko, EV ^{[1
]}

Stonik, VA ^{[1
]}

机构：

[1] Russian Acad Sci, Far Eastern Branch, Pacific Inst Bioorgan Chem, Vladivostok 690022, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2004年 / 53卷 / 11期

基金：

俄罗斯基础研究基金会;

关键词：

starfishes; Hippasteria phrygiana; polyhydroxysteroids; sulfated polyhydroxy steroids; steroids; glycosides; aglycones; FAB; MALDI-TOF; H-1; NMR; and C-13 NMR spectra;

D O I：

10.1007/s11172-005-0165-z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three polyhydroxylated steroids were isolated from the Far-Eastern starfish Hippasteria phrygiana collected from the Sea of Okhotsk and were characterized as a new glycoside phrygioside A, viz., sodium (20R, 24S)-3 beta,4 beta,7 alpha,8,15 beta,24-hexahydroxy-24-O-[3-O-methyl-beta-D-xylopyranosyl-(1 -> 2)-alpha-L-arabinofuranosyl]-5 alpha-cholestan-6 alpha-yl sulfate, its aglycone, and the already known marthasterone sulfate.

引用

页码：2634 / 2638

页数：5

共 11 条

[1]

Correa R. S. D., 1985, J NAT PRODUCTS, V48, P751

[2] Isolation, structure elucidation, and biological activity of the steroid oligoglycosides and polyhydroxysteroids from the Antarctic starfish Acodontaster conspicuus [J].

DeMarino, S ;

Iorizzi, M ;

Zollo, F ;

Minale, L ;

Amsler, CD ;

Baker, BJ ;

McClintock, JB .

JOURNAL OF NATURAL PRODUCTS, 1997, 60 (10) :959-966

[3]

IORIZZI M, 1990, GAZZ CHIM ITAL, V120, P147

[4] STARFISH SAPONINS .48. ISOLATION OF 9 STEROL CONSTITUENTS (6 GLYCOSIDES AND 9 POLYHYDROXYSTEROIDS) FROM THE STARFISH SOLASTER-BOREALIS [J].

IORIZZI, M ;

MINALE, L ;

RICCIO, R .

JOURNAL OF NATURAL PRODUCTS, 1992, 55 (07) :866-877

[5]

Kicha A. A., 1984, KHIM PRIR SOEDIN, V6, P738

[6]

KICHA AA, 1985, KHIM PRIR SOEDIN, V6, P801

[7] Steroid compounds from the Pacific starfish Lysastrosoma anthosticta [J].

Levina, EV ;

Andriyashchenko, PV ;

Kalinovskii, AI ;

Stonik, VA .

RUSSIAN CHEMICAL BULLETIN, 2001, 50 (02) :313-315

[8]

LEVINA EV, 2003, IZV AKAD NAUK SER KH, P1539

[9]

MICHEEL F, 1956, CHEM ZUCKER POLYSACC

[10]

MINALE L, 1984, GAZZ CHIM ITAL, V114, P143

← 1 2 →