[η5-1,3-Bis(trimethylsilyl)cyclopentadienyl]dichlorido[η5-(trimethylsilyl)cyclopentadienyl]titanium(IV)

被引：0
作者：
Perdih, Franc [1 ,2 ]
机构：
[1] Univ Ljubljana, Fac Chem & Chem Technol, SI-1000 Ljubljana, Slovenia
[2] CO EN FIST, SI-1000 Ljubljana, Slovenia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
METALLOCENE COMPLEXES; OLEFIN POLYMERIZATION; MOLECULAR-STRUCTURE; DERIVATIVES; DICHLORIDE; CATALYSTS; CRYSTAL;
D O I：
10.1107/S1600536811046228
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Ti(C8H13Si)(C11H21Si2)Cl-2], the Ti-IV atom is bonded to two Cl atoms, one 1,3-bis(trimethylsilyl)cyclopentadienyl (Si2Cp) and one (trimethylsilyl) cyclopentadienyl ring (SiCp). The Si2Cp centroid-titanium distance is 2.0763 (10) angstrom and the SiCp centroid-titanium distance is 2.0793 (10) angstrom. The angle subtended at the Ti atom by the centroids of both cyclopentadienyl rings is 131.22 (4)degrees and the Cl-Ti-Cl angle is 94.14 (2)degrees.
引用
收藏
页码：M1693 / U1374
页数：15
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