Sodiation-Desodiation Reactions of Various Binary Phosphides as Novel Anode Materials of Na-Ion Battery

被引：38

作者：

Usui, Hiroyuki ^{[1
,3
]}

Domi, Yasuhiro ^{[1
,3
]}

Yarnagarni, Ryota ^{[2
,3
]}

Fujiwara, Kohei ^{[1
,3
]}

Nishida, Haruka ^{[1
,3
]}

Sakaguchi, Hiroki ^{[1
,3
]}

机构：

[1] Tottori Univ, Grad Sch Engn, Dept Chem & Biotechnol, 4-101 Minami,Koyama Cho, Tottori 6808552, Japan

[2] Tottori Univ, Grad Sch Sustainabil Sci, Dept Engn, Course Chem & Biotechnol, 4-101 Minami,Koyama Cho, Tottori 6808552, Japan

[3] Tottori Univ, Ctr Res Green Sustainable Chem, 4-101 Minami,Koyama Cho, Tottori 6808552, Japan

来源：

ACS APPLIED ENERGY MATERIALS | 2018年 / 1卷 / 02期

基金：

日本学术振兴会;

关键词：

binary phosphide compounds; indium phosphide; Na-ion battery; anode material; nanostructure; INSERTION/EXTRACTION PROPERTIES; NEGATIVE ELECTRODE; HARD-CARBON; LIQUID ELECTROLYTE; BLACK PHOSPHORUS; HIGH-CAPACITY; SILICON; STORAGE; SN4P3;

D O I：

10.1021/acsaem.7b00241

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sodiation-desodiation behaviors were investigated for electrodes composed of various binary phosphides, InP, CuP2, GeP, SiP, and LaP, as anode materials of a Na-ion battery. Although LaP electrode did not react with Na, the other electrodes showed reversible sodiation-desodiation reactions in the initial cycles. Rapid capacity decays were observed for CuP2, GeP, and SiP electrodes. In contrast, a better cyclability was attained for the InP electrode. These results indicate that binary phosphides (M-P) require four properties for improving cyclability: (i) low thermodynamic stability of M-P, (ii) high electronic conductivity of M, (iii) low hardness of M, and (iv) reactivity of M with Na.

引用

页码：306 / 311

页数：11

共 30 条

[1] High performance red phosphorus electrode in ionic liquid-based electrolyte for Na-ion batteries [J].

Dahbi, Mouad ;

Fukunishi, Mika ;

Horiba, Tatsuo ;

Yabuuchi, Naoaki ;

Yasuno, Satoshi ;

Komaba, Shinichi .

JOURNAL OF POWER SOURCES, 2017, 363 :404-412

[2] Synthesis of hard carbon from argan shells for Na-ion batteries [J].

Dahbi, Mouad ;

Kiso, Manami ;

Kubota, Kei ;

Horiba, Tatsuo ;

Chafik, Tarik ;

Hida, Kazuo ;

Matsuyama, Takashi ;

Komaba, Shinichi .

JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (20) :9917-9928

[3] Black Phosphorus as a High-Capacity, High-Capability Negative Electrode for Sodium-Ion Batteries: Investigation of the Electrode/Interface [J].

Dahbi, Mouad ;

Yabuuchi, Naoaki ;

Fukunishi, Mika ;

Kubota, Kei ;

Chihara, Kuniko ;

Tokiwa, Kazuyasu ;

Yu, Xue-fang ;

Ushiyama, Hiroshi ;

Yamashita, Koichi ;

Son, Jin-Young ;

Cui, Yi-Tao ;

Oji, Hiroshi ;

Komaba, Shinichi .

CHEMISTRY OF MATERIALS, 2016, 28 (06) :1625-1635

[4] Sodium carboxymethyl cellulose as a potential binder for hard-carbon negative electrodes in sodium-ion batteries [J].

Dahbi, Mouad ;

Nakano, Takeshi ;

Yabuuchi, Naoaki ;

Ishikawa, Toru ;

Kubota, Kei ;

Fukunishi, Mika ;

Shibahara, Sota ;

Son, Jin-Young ;

Cui, Yi-Tao ;

Oji, Hiroshi ;

Komaba, Shinichi .

ELECTROCHEMISTRY COMMUNICATIONS, 2014, 44 :66-69

[5] In Situ XRD Study of Silicon, Lead and Bismuth Negative Electrodes in Nonaqueous Sodium Cells [J].

Ellis, L. D. ;

Wilkes, B. N. ;

Hatchard, T. D. ;

Obrovac, M. N. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2014, 161 (03) :A416-A421

[6] The origin of excellent rate and cycle performance of Sn4P3 binary electrodes for sodium-ion batteries [J].

Jung, Sung Chul ;

Choi, Jin-Ho ;

Han, Young-Kyu .

JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (04) :1772-1779

[7] Atom-Level Understanding of the Sodiation Process in Silicon Anode Material [J].

Jung, Sung Chul ;

Jung, Dae Soo ;

Choi, Jang Wook ;

Han, Young-Kyu .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (07) :1283-1288

[8] Electrochemical sodium storage in amorphous GeOx powder [J].

Kajita, Tetsuya ;

Itoh, Takashi .

ELECTROCHIMICA ACTA, 2016, 195 :192-198

[9] Tin Phosphide as a Promising Anode Material for Na-Ion Batteries [J].

Kim, Youngjin ;

Kim, Yongil ;

Choi, Aram ;

Woo, Sangwon ;

Mok, Duckgyun ;

Choi, Nam-Soon ;

Jung, Yoon Seok ;

Ryu, Ji Heon ;

Oh, Seung M. ;

Lee, Kyu Tae .

ADVANCED MATERIALS, 2014, 26 (24) :4139-4144

[10] Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries [J].

Komaba, Shinichi ;

Murata, Wataru ;

Ishikawa, Toru ;

Yabuuchi, Naoaki ;

Ozeki, Tomoaki ;

Nakayama, Tetsuri ;

Ogata, Atsushi ;

Gotoh, Kazuma ;

Fujiwara, Kazuya .

ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (20) :3859-3867

← 1 2 3 →