Nonlinear optical activity and high thermal stability of a new 3D open-framework with interconnected 24-, 16-, and 8-atom channels:: (NH4)Zn[O3PCH(OH)CO2]

被引：40

作者：

Fu, RB ^{[1
]}

Zhang, HS ^{[1
]}

Wang, LS ^{[1
]}

Hu, SM ^{[1
]}

Li, YM ^{[1
]}

Huang, XH ^{[1
]}

Wu, XT ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 16期

关键词：

zinc; hydroxy(phosphonoato)acetate; nonlinear optical activity; hydrothermal synthesis; open-framework;

D O I：

10.1002/ejic.200500347

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrothermal. reaction of hydroxy(phosphono)acetic acid, H2O3PCH(OH)CO2H, with zinc(II) acetate resulted in a new ammonium zinc hydroxy(phosphonato) acetate, (NH4)-Zn[O3PCH(OH)CO2] (1). The structure of 1 contains a 3D open-framework consisting of interconnected 24-, 16-, and 8-atom channels. TGA and XRD reveal that the framework is stable up to 350 degrees C in air. Its powder SHG intensity is about 0.8 times that of potassium dihydrogen phosphate KDR ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).

引用

页码：3211 / 3213

页数：3

共 14 条

[1]

[Anonymous], J APPL PHYS

[2] Crystal engineering of NLO materials based on metal-organic coordination networks [J].

Evans, OR ;

Lin, WB .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522

[3] An unprecedented 3D coordination network composed of two intersecting helices [J].

Evans, OR ;

Wang, ZY ;

Lin, WB .

CHEMICAL COMMUNICATIONS, 1999, (18) :1903-1904

[4]

Evans OR, 1999, ANGEW CHEM INT EDIT, V38, P536, DOI 10.1002/(SICI)1521-3773(19990215)38:4<536::AID-ANIE536>3.0.CO

[5]

2-3

[6] Rational design of nonlinear optical materials based on 2D coordination networks [J].

Evans, OR ;

Lin, WB .

CHEMISTRY OF MATERIALS, 2001, 13 (09) :3009-3017

[7] Crystal engineering of nonlinear optical materials based on interpenetrated diamondoid coordination networks [J].

Evans, OR ;

Lin, WB .

CHEMISTRY OF MATERIALS, 2001, 13 (08) :2705-2712

[8] A novel nonlinear optically active tubular coordination network based on two distinct homo-chiral helices [J].

Han, L ;

Hong, MC ;

Wang, RH ;

Luo, JH ;

Lin, ZZ ;

Yuan, DQ .

CHEMICAL COMMUNICATIONS, 2003, (20) :2580-2581

[9] A novel ligand-unsupported 3D framework polymer of trimeric copper(I)) and its NLO property [J].

Kang, Y ;

Yao, YG ;

Qin, YY ;

Zhang, J ;

Chen, YB ;

Li, ZJ ;

Wen, YH ;

Cheng, JK ;

Hu, RF .

CHEMICAL COMMUNICATIONS, 2004, (09) :1046-1047

[10] Supramolecular engineering of chiral and acentric 2D networks. Synthesis, structures, and second-order nonlinear optical properties of bis(nicotinato)zinc and bis{3-[2-(4-pyridyl)ethenyl]benzoato}cadmium [J].

Lin, WB ;

Evans, OR ;

Xiong, RG ;

Wang, ZY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (50) :13272-13273

← 1 2 →