Diaquabis(1,10-phenanthroline-κ2N,N′)cadmium(II) pentafluorooxoniobate(V)

被引:4
作者
Zhu, G [1 ]
Tang, ZX [1 ]
机构
[1] NW Univ Xian, Dept Chem, Shaanxi Key Lab Physicoinorgan Chem, Xian 710069, Peoples R China
关键词
D O I
10.1107/S1600536805030394
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The crystal structure of the title compound, [ Cd( C12H8N2)(2)( H2O)(2)][ NbOF5], consists of Cd-II complex cations and Nb-V complex anions. The Cd-II and NbV atoms both have a distorted octahedral geometry. The Nb - F bond trans to the Nb = O bond is significantly longer than the other four Nb - F bonds.
引用
收藏
页码:M2118 / M2120
页数:3
相关论文
共 11 条
[1]  
*BRUK AXS INC, 2002, SAINT SMART
[2]   Composition space of the (CuO, 1/2Nb(2)O(5))/(HF)(x)center dot pyridine/H2O system. Structure and synthesis of [pyH(+)](2)[CuNb2(py)(4)O2F10](2-) and CuNb(py)(4)OF5 [J].
Halasyamani, P ;
Willis, MJ ;
Stern, CL ;
Lundquist, PM ;
Wong, GK ;
Poeppelmeier, KR .
INORGANIC CHEMISTRY, 1996, 35 (05) :1367-1371
[3]   [pyH]2[Cu(py)4(MX6)2] (MX6 = ZrF62-, NbOF52-, MoO2F42-;: py equals pyridine):: Rarely observed ordering of metal oxide fluoride anions [J].
Heier, KR ;
Norquist, AJ ;
Wilson, CG ;
Stern, CL ;
Poeppelmeier, KR .
INORGANIC CHEMISTRY, 1998, 37 (01) :76-80
[4]   Examining the out-of-center distortion in the [NbOF5]2- anion [J].
Izumi, HK ;
Kirsch, JE ;
Stern, CL ;
Poeppelmeier, KR .
INORGANIC CHEMISTRY, 2005, 44 (04) :884-895
[5]   Cu(C10H9N3)2MOF5•2H2O (M = Nb, Ta):: Aligned [MOF5]2- oxide fluoride anions [J].
Norquist, AJ ;
Stern, CL ;
Poeppelmeier, KR .
INORGANIC CHEMISTRY, 1999, 38 (15) :3448-3449
[6]  
Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR
[7]  
Sheldrick G.M., 2002, SAINT (Version 6.02), SADABS (Version 2.03)
[8]   PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].
SHELDRICK, GM .
ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473
[9]  
*SIEM, 1995, SHELXTL VERS 5 03
[10]  
*SIEM, 1994, XP VERS 5 03