Silver nanoparticle-embedded RGO-nanosponge for superior catalytic activity towards 4-nitrophenol reduction

被引:46
作者
Vellaichamy, Balakumar [1 ]
Periakaruppan, Prakash [1 ]
机构
[1] Thiagarajar Coll, Dept Chem, Madurai 625009, Tamil Nadu, India
来源
RSC ADVANCES | 2016年 / 6卷 / 91期
关键词
CORE-SHELL NANOPARTICLES; GOLD NANOPARTICLES; GREEN SYNTHESIS; GRAPHENE OXIDE; ONE-POT; AG NANOPARTICLES; EFFICIENT; CARBON; AU; NANOSTRUCTURES;
D O I
10.1039/c6ra19834a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The present work highlights a bio-inspired synthesis of uniform 2 nm sized plasmonic silver nanospheres (Ag-NSs) embedded in reduced graphene oxide nanosponge (RGONS) using Tabebuia berteroi leaf extract. The green reduced RGONS/Ag-NSs is very clean and displays a fabulous catalytic activity towards the reduction of 4-nitrophenol (4-NP) in the presence of ice cold NaBH4 solution. Various analytical techniques were adopted to confirm the composition and structure of the crystalline nanocatalyst materials, including UV-visible absorption spectroscopy, FT-IR, XRD, Raman spectroscopy, HR-TEM and EDX. The formation of Ag-NSs, RGONS and RGONS/Ag-NSs, catalytic mechanism, stability and reusability of the catalyst were also investigated. The catalytic activity of RGONS/Ag-NSs is found to be superior to that ever reported.
引用
收藏
页码:88837 / 88845
页数:9
相关论文
共 60 条
  • [1] Agileo H. G., 2015, CHEM ENG J, V261, P53
  • [2] Catalytic reduction of 4-nitrophenol by silver nanoparticles stabilized on environmentally benign macroscopic biopolymer hydrogel
    Ai, Lunhong
    Jiang, Jing
    [J]. BIORESOURCE TECHNOLOGY, 2013, 132 : 374 - 377
  • [3] Honeycomb Carbon: A Review of Graphene
    Allen, Matthew J.
    Tung, Vincent C.
    Kaner, Richard B.
    [J]. CHEMICAL REVIEWS, 2010, 110 (01) : 132 - 145
  • [4] Chitosan based polymer matrix with silver nanoparticles decorated multiwalled carbon nanotubes for catalytic reduction of 4-nitrophenol
    Alshehri, Saad M.
    Almuqati, Turki
    Almuqati, Naif
    Al-Farraj, Eida
    Alhokbany, Norah
    Ahamad, Tansir
    [J]. CARBOHYDRATE POLYMERS, 2016, 151 : 135 - 143
  • [5] *ATSDR, 1990, TOX PROF NITR DRAFT
  • [6] Balandin AA, 2011, NAT MATER, V10, P569, DOI [10.1038/nmat3064, 10.1038/NMAT3064]
  • [7] Hydrogenolysis of sorbitol over Ni and Pt loaded on NaY
    Banu, M.
    Sivasanker, S.
    Sankaranarayanan, T. M.
    Venuvanalingam, P.
    [J]. CATALYSIS COMMUNICATIONS, 2011, 12 (07) : 673 - 677
  • [8] Novel synthesis route for Ag@SiO2 core-shell nanoparticles via micelle template of double hydrophilic block copolymer
    Bastakoti, Bishnu Prasad
    Guragain, Sudhina
    Yusa, Shin-ichi
    Nakashima, Kenichi
    [J]. RSC ADVANCES, 2012, 2 (14) : 5938 - 5940
  • [9] Toward greener nanosynthesis
    Dahl, Jennifer A.
    Maddux, Bettye L. S.
    Hutchison, James E.
    [J]. CHEMICAL REVIEWS, 2007, 107 (06) : 2228 - 2269
  • [10] Silver nanoparticles immobilized on fibrous nano-silica as highly efficient and recyclable heterogeneous catalyst for reduction of 4-nitrophenol and 2-nitroaniline
    Dong, Zhengping
    Le, Xuanduong
    Li, Xinlin
    Zhang, Wei
    Dong, Chunxu
    Ma, Jiantai
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 158 : 129 - 135