Removal of tartrazine from aqueous solutions using adsorbents based on activated carbon and Moringa oleifera seeds

被引:144
作者
Reck, Isabela Maria [1 ]
Paixao, Rebecca Manesco [2 ]
Bergamasco, Rosangela [2 ]
Vieira, Marcelo Fernandes [2 ]
Salcedo Vieira, Angelica Marquetotti [3 ]
机构
[1] Univ Estadual Maringa, UEM, Postgrad Program Food Sci, Av Colombo 5790, BR-87020900 Maringa, Parana, Brazil
[2] Univ Estadual Maringa, UEM, Dept Chem Engn, Av Colombo 5790, BR-87020900 Maringa, Parana, Brazil
[3] Univ Estadual Maringa, UEM, Dept Food Engn, Av Colombo 5790, BR-87020900 Maringa, Parana, Brazil
关键词
Biosorbents; Tartrazine dye; Moringa oleifera; Babassu carbon; Bone carbon; METHYLENE-BLUE DYE; ADSORPTION-KINETICS; HEAVY-METALS; WASTE-WATER; PEEL WASTE; SORPTION; ISOTHERM; VIOLET; GASES;
D O I
10.1016/j.jclepro.2017.09.237
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this study, a new and low-cost adsorbent, obtained from the Moringa oleifera seed, was compared to activated carbons of babassu coconut (ACBC) and bone (ABC), to remove dye from aqueous solution. Brunauer-Emmet-Teller analysis, scanning electron microscopy and X-ray diffraction were used to characterize the adsorbents. Adsorption with Moringa oleifera was able to remove more than 95% of the dye, reaching a maximum capacity of 91.27 mg g(-1) at 15 degrees C. The results demonstrate that the kinetic data were well described by the models of pseudo-second order for the activated carbon of babassu coconut and pseudo-first order for both Moringa oleifera seeds and activated bone carbon. Isothermal data using the Langmuir and Freundlich equations were adjusted, with a better fit to the experimental data given by the Freundlich equation. The thermodynamic parameters show that adsorption is an endothermic process for both carbon materials and an exothermic process for the Moringa oleifera seeds. An actual wastewater assay was performed demonstrating the effectiveness of the Moringa adsorbent. This results show that Moringa oleifera seeds can be an effective alternative to the use of activated carbon for dye removal in contaminated waters, since it is a natural adsorbent and does not undergo the carbon activation processes. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:85 / 97
页数:13
相关论文
共 53 条
[21]   Production and Characterization of Adsorbent Materials from Sewage Sludge by Pyrolysis [J].
De Filippis, Paolo ;
Di Palma, Luca ;
Petrucci, Elisabetta ;
Scarsella, Marco ;
Verdone, Nicola .
ICHEAP-11: 11TH INTERNATIONAL CONFERENCE ON CHEMICAL AND PROCESS ENGINEERING, PTS 1-4, 2013, 32 :205-210
[22]   Factors affecting sorption of organic compounds in natural sorbent/water systems and sorption coefficients for selected pollutants. A review [J].
Delle Site, A .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 2001, 30 (01) :187-439
[23]   Isotherm and thermodynamic data of adsorption of methylene blue from aqueous solution onto peat [J].
Fernandes, Andreia Neves ;
Policiano Almeida, Carlos Alberto ;
Debacher, Nito Angelo ;
de Souza Sierra, Maria Marta .
JOURNAL OF MOLECULAR STRUCTURE, 2010, 982 (1-3) :62-65
[24]  
Formentini-Schmitt D. M., 2013, WATER AIR SOIL POLL, P224
[25]  
Freundlich H, 1906, Z PHYS CHEM-STOCH VE, V57, P385
[26]   Preparation of activated carbon from Alligator weed (Alternenthera philoxeroids) and its application for tartrazine removal: Isotherm, kinetics and spectroscopic analysis [J].
Gautam, Pavan Kumar ;
Gautam, Ravindra Kumar ;
Banerjee, Sushmita ;
Lofrano, Giusy ;
Sanroman, Maria Angeles ;
Chattopadhyaya, Mahesh Chandra ;
Pandey, J. D. .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2015, 3 (04) :2560-2568
[27]   Removal of tartrazine by activated carbon biosorbents of Lantana camara: Kinetics, equilibrium modeling and spectroscopic analysis [J].
Gautam, Ravindra Kumar ;
Gautam, Pavan Kumar ;
Banerjee, Sushmita ;
Rawat, Vandani ;
Soni, Shivani ;
Sharma, Sanjay K. ;
Chattopadhyaya, Mahesh Chandra .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2015, 3 (01) :79-88
[28]   Ordered mesoporous carbons modified with cerium as effective adsorbents for azo dyes removal [J].
Goscianska, Joanna ;
Marciniak, Michal ;
Pietrzak, Robert .
SEPARATION AND PURIFICATION TECHNOLOGY, 2015, 154 :236-245
[29]   The potential for the use of waste products from a variety of sectors in water treatment processes [J].
Grace, Maebh A. ;
Clifford, Eoghan ;
Healy, Mark G. .
JOURNAL OF CLEANER PRODUCTION, 2016, 137 :788-802
[30]   Removal of Tartrazine Dye onto Mixed-Waste Activated Carbon: Kinetic and Thermodynamic Studies [J].
Habila, Mohamed Abdelaty ;
ALOthman, Zeid Abdullah ;
Ali, Rahmat ;
Ghafar, Ayman Abdel ;
Hassouna, Mohamed Slah El-Din .
CLEAN-SOIL AIR WATER, 2014, 42 (12) :1824-1831